86664-80-4

Upstream product

• 25702-61-8 ReH₅(P(C₆H₅)3)2(NH₂C₆H₁₁) 
• 75-05-8 acetonitrile 

Downstream Products

• 91279-49-1 Re(CNC₄H₉)4(P(C₆H₅)3)2⁽¹⁺⁾*BF₄^(1-) 
• 91229-70-8 ReH(NCCH₃)2(CNC₄H₉)(NH₂C₆H₁₁)(P(C₆H₅)3)2⁽²⁺⁾*2BF₄^(1-) 

Relevant academic research and scientific papers

Protonation Reactions of the Mononuclear Rhenium Polyhydride Complexes , (L=Unidentate Ligand), and

Protonation of the rhenium polyhydride complexes , t>, or with HBF4.Et2O in acetonitrile or propionitrile leads to the seven-co-ordinate complexes ReH(NCR)3(PPh3)

Activation of Mono- and Di-nuclear Polyhydrides of Rhenium: Protonation, Solvation, and Oxidation

Activation of the rhenium polyhydrides ReH5(PPh3)2L (L=monodentate ligand) and Re2H8(PPh3)4 has been achieved through their protonation (using HBF4), the formation of solvento-complexes, and their oxidation to reactive paramagnetic cations, strategies which have led to a range of novel species, including 2+, +, and t)2>+ together with their '17-electron' paramagnetic congeners.