866641-64-7

Basic information

• Product Name: [(o-biphenylPCy₂)Au(NCMe)]SbF₆
• CAS NO: 866641-64-7
• Molecular Weight: 824.243
• Mol File: 866641-64-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(o-biphenylPCy₂)Au(NCMe)]SbF₆(CAS DataBase Reference)
• NIST Chemistry Reference: [(o-biphenylPCy₂)Au(NCMe)]SbF₆(866641-64-7)
• EPA Substance Registry System: [(o-biphenylPCy₂)Au(NCMe)]SbF₆(866641-64-7)

Safety Data

• Hazardous Substances Data: 866641-64-7(Hazardous Substances Data)

Upstream product

• 26042-64-8 silver hexafluoroantimonate 
• 854045-92-4 chloro([1,1'-biphenyl]-2-yldicyclohexylphosphine)gold(I) 
• 75-05-8 acetonitrile 

Relevant articles and documents

Tandem gold/silver-catalyzed cycloaddition/hydroarylation of 7-aryl-1,6-enynes to form 6,6-diarylbicyclo[3.2.0]heptanes

Mixtures of [{PCy2(o-biphenyl)}AuCl] and AgSbF6 catalyze the tandem cycloaddition/hydroarylation of 7-aryl-1,6-enynes with electron-rich arenes to form 6,6-diarylbicyclo[3.2.0]heptanes in good yield under mild conditions. Experimental observations point to a mechanism involving gold-catalyzed cycloaddition followed by silver-catalyzed hydroarylation of a bicyclo[3.2.0]hept-1(7)-ene intermediate.