866719-69-9

Upstream product

• 545-06-2 trichloroacetonitrile 
• 185994-24-5 phenyl 2,3,4-tri-O-benzoyl-6-O-(t-butyldiphenylsilyl)-1-thio-β-D-glucopyranoside 
• 1029696-25-0 phenyl 2,3,4-tri-O-benzoyl-6-O-(tert-butyldiphenylsilyl)-1-thio-α-D-glucopyranoside 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 2280-44-6 D-Glucose 
• 98-88-4 benzoyl chloride 

Downstream Products

• 943234-28-4 methyl O-[O-(2,3,4-tri-O-benzoyl-6-O-(tert-butyldiphenylsilyl)-β-D-glucopyranosyl)-(1->6)-(2,3,4-tri-O-benzoyl-β-D-glucopyranosyl)]-(1->6)-(2,3,4-tri-O-octadecanoyl-α-D-glucopyranoside 
• 943234-27-3 methyl O-{O-[O-(2,3,4-tri-O-benzoyl-6-O-(tert-butyldiphenylsilyl)-β-D-glucopyranosyl)-(1->6)-(2,3,4-tri-O-benzoyl-β-D-glucopyranosyl)]-(1->6)-(2,3,4-tri-O-benzoyl-β-D-glucopyranosyl)}-(1->6)-2,3,4-tri-O-octadecanoyl-α-D-glucopyranoside 
• 915309-09-0 methyl O-(2,3,4-tri-O-benzoyl-6-O-(tert-butyldiphenylsilyl)-β-D-glucopyranosyl)-(1->6)-2,3,4-tri-O-octadecanoyl-α-D-glucopyranoside 
• 914102-37-7 pent-4-enyl 2,3,4-tri-O-benzoyl-β-D-glucopyranoside 
• 866719-67-7 C₂₉H₂₄Cl₃NO₉ 

Relevant academic research and scientific papers

N-Pentenyl-Type Glycosides for Catalytic Glycosylation and Their Application in Single-Catalyst One-Pot Oligosaccharide Assemblies

We have developed a new type of n-pentenyl-type glycosides that can be activated by catalytic amounts of promoter, Hg(NTf2)2 or PPh3AuCl/AgNTf2, at room temperature. The mild activation conditions and outstanding stability of common protection/deprotection manipulations enable the enynyl donors to have broad applications in constructing various glycosidic bonds. Furthermore, under the Hg(NTf2)2-catalyzed conditions, the sequential activation of different types of donors was achieved, based on which a gentiotetrasaccharide was synthesized via the newly developed single-catalyst one-pot strategy.

Solution-phase oligosaccharide synthesis in a cycloalkane-based thermomorphic system

The cycloalkane-based thermomorphic (CBT) system is a convenient and practical method for oligosaccharide synthesis, and hydrophobically modified oligosaccharides have a remarkable affinity for CBT solutions composed of methylcyclohexane and propionitrile

Some aspects of selectivity in the reaction of glycosyl donors

Some advantages, disadvantages, and anomalies of various donors in glycosidations are discussed. By studying several two-component donor/acceptor-diol reactions, it is shown that regiopreferences are not very sensitive to the type of donor used. However,