866751-78-2

Basic information

• Product Name: Ag⁽¹⁺⁾*N₂OC₂(C₆H₄CCH)2*BF₄^(1-)=(Ag(N₂OC₂(C₆H₄CCH)2))BF₄
• CAS NO: 866751-78-2
• Molecular Weight: 464.963
• Mol File: 866751-78-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ag⁽¹⁺⁾*N₂OC₂(C₆H₄CCH)2*BF₄^(1-)=(Ag(N₂OC₂(C₆H₄CCH)2))BF₄(CAS DataBase Reference)
• NIST Chemistry Reference: Ag⁽¹⁺⁾*N₂OC₂(C₆H₄CCH)2*BF₄^(1-)=(Ag(N₂OC₂(C₆H₄CCH)2))BF₄(866751-78-2)
• EPA Substance Registry System: Ag⁽¹⁺⁾*N₂OC₂(C₆H₄CCH)2*BF₄^(1-)=(Ag(N₂OC₂(C₆H₄CCH)2))BF₄(866751-78-2)

Safety Data

• Hazardous Substances Data: 866751-78-2(Hazardous Substances Data)

Upstream product

• 14104-20-2 silver tetrafluoroborate 
• 817171-72-5 2,5-bis-(4-ethynylphenyl) [1,3,4]oxadiazole 

Relevant articles and documents

Organometallic coordination polymers generated from bent bis(acetylenylphenyl)oxadiazole ligands and Ag(I) salts

Two new bent oxadiazole bridging benzoacetylene ligands 2,5-bis(4-ethynylphenyl)-1,3,4-oxadiazole (L9) and 2,5-bis(3-ethynylphenyl)-1,3, 4-oxadiazole (L10) were synthesized. The coordination chemistry of them with various inorganic Ag(I) salts has been investigated. Seven new coordination polymers were prepared by solution reactions and fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. [Ag2(L9)]-(SO3CF3)2 (1) (triclinic, P1; a = 10.292(4), b = 10.794(4), c = 11.399(5) A; α = 98.894(5), β = 102.360(6), γ = 90.319(5)°; Z = 2), [Ag(L9)]SbF6 (2) (orthorhombic, Cmca; a = 19.059(9), b = 12.922(6), c = 15.609(7) A; Z = 8), [Ag(L9)]BF4 (3) (orthorhombic, Cmca; a = 19.128(3), b = 12.6042(18), c = 28.003(4) A; Z = 16), [Ag(L9)]ClO4 (4) (monoclinic, P21/c; a = 8.5153(16), b = 19.722(4), c = 10.320(2) A; β = 105.307(3)°; Z = 4), [Ag(L10)]-SO3CF 3 (5) (triclinic, P1; a = 9.0605(13), b = 10.4956(15), c = 10.8085(16) A; α = 101.666(2), β = 109.269(2), γ = 100.944(2)°; Z = 2), [Ag(L10)(H2O)0.5]BF 4·0.5H2O (6) (monoclinic, C2/m; a = 32.180(6), b = 17.027(3), c = 8.1453(15) A; β = 102.541(3)°; Z = 8), and {[Ag2(L10)2(H2O)](ClO4) 2}·o-xylene (7) (monoclinic, P21/c; a = 8.1460(10), b = 17.326(2), c = 30.345(4) A; β = 97.71°; Z = 4) were obtained by the combination of L9 and L10 with various Ag(I) salts in a benzene/methylene chloride mixed solvent system. In addition, the luminescent and electrical conductive properties of these new compounds were investigated.