866890-76-8

Basic information

• Product Name: (3aR,5S,6R,6aR)-6-(2-bromo-4,5-dimethoxy-benzyloxy)-5-iodomethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole
• CAS NO: 866890-76-8
• Molecular Weight: 529.167
• Mol File: 866890-76-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3aR,5S,6R,6aR)-6-(2-bromo-4,5-dimethoxy-benzyloxy)-5-iodomethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole(CAS DataBase Reference)
• NIST Chemistry Reference: (3aR,5S,6R,6aR)-6-(2-bromo-4,5-dimethoxy-benzyloxy)-5-iodomethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole(866890-76-8)
• EPA Substance Registry System: (3aR,5S,6R,6aR)-6-(2-bromo-4,5-dimethoxy-benzyloxy)-5-iodomethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole(866890-76-8)

Safety Data

• Hazardous Substances Data: 866890-76-8(Hazardous Substances Data)

Upstream product

• 417702-87-5 (3aR,5R,6S,6aR)-6-(2-bromo-4,5-dimethyloxy-benzyloxy)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydrofuro[2,3-d][1,3]dioxole 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 53207-00-4 1-bromo-2-(bromomethyl)-4,5-dimethoxybenzene 

Relevant articles and documents

Radical cyclization of exo-methylene furanose derivatives: An expedient approach to the synthesis of chiral tricyclic nucleosides and benzannulated oxepine derivatives

Tributyltin radical mediated cyclization of the glucose derived exo-methylene furanose derivatives 5a-c led to the highly functionalized cis-fused bicyclic ethers 6a-c. The product could subsequently be transformed to the optically active tricyclic nucleoside analogue 8 or oxepine derivative 9.