866918-71-0Relevant academic research and scientific papers
Stable reagents for the generation of N-centered radicals: Hydroamination of norbornene
Kemper, Jens,Studer, Armido
, p. 4914 - 4917 (2005)
(Chemical Equation Presented) Radical transfer hydroaminations have been achieved with 3-aminated 1,4-cyclohexadienes rather than transition-metal reagents (see scheme; DTBP = di-tert-butylperoxide). These functionalized cyclohexadienes are efficient N-radical precursors. Moreover, they are stable and readily prepared, and radical generation occurs under neutral conditions.
