86702-28-5

Usage

Uses

Used in Pharmaceutical Industry:
2-(acetyloxy)-1-[(benzoyloxy)methyl]-7-oxabicyclo[4.1.0]hept-4-en-3-yl benzoate is used as a pharmaceutical intermediate for the synthesis of various drugs. Its unique structure and functional groups make it a valuable building block in the development of new medicinal compounds, potentially leading to the creation of novel therapeutic agents.
Used in Organic Synthesis:
In the field of organic synthesis, 2-(acetyloxy)-1-[(benzoyloxy)methyl]-7-oxabicyclo[4.1.0]hept-4-en-3-yl benzoate serves as a key intermediate in the preparation of complex organic molecules. Its multiple functional groups allow for a variety of chemical reactions, enabling the synthesis of a wide range of organic compounds.
Used as a Reagent in Chemical Reactions:
2-(acetyloxy)-1-[(benzoyloxy)methyl]-7-oxabicyclo[4.1.0]hept-4-en-3-yl benzoate is utilized as a reagent in various chemical reactions, facilitating the formation of desired products. Its presence can enhance reaction efficiency and selectivity, making it a useful component in the synthesis of specific chemical entities.

Upstream product

• 86702-29-6 (2R)-trans-2-acetoxy-3-(benzoyloxy)-1-<(benzoyloxy)methyl>cyclohexa-4,6-diene 
• 98-88-4 benzoyl chloride 
• 85966-24-1 (2R)-trans-3-(benzoyloxy)-1-<(benzoyloxy)methyl>-2-hydroxycyclohexa-4,6-diene 
• 96247-02-8 (2R)-trans-2-acetoxy-3-hydroxy-1-[(benzoyloxy)methyl]cyclohexa-4,6-diene 
• 131221-89-1 (1R,2R,3S)-3-O-tert-Butyldimethylsilyl-1,2-O-cyclohexylidene-5-hydroxymethyl-4-cyclohexen-1,2,3-triol 
• 130021-74-8 (1R,2R,3S)-1,2-O-Cyclohexylidene-5-hydroxymethyl-4-cyclohexen-1,2,3-triol 
• 203457-70-9 Benzoic acid (1S,2S,3R,6S)-2-acetoxy-3-hydroxy-7-oxa-bicyclo[4.1.0]hept-4-en-1-ylmethyl ester 
• 203457-68-5 Benzoic acid (1R,2S,3R,6R)-2-acetoxy-3-hydroxy-7-oxa-bicyclo[4.1.0]hept-4-en-1-ylmethyl ester 
• 174966-55-3 (1R,2S,3S,4R,5R)-3-O-tert-butyldimethylsilyl-1-benzoyloxymethyl-4,5-O-cyclohexylidene-1,2,3,4,5-cyclohexanepentaol 
• 174966-54-2 (1R,2R,3S)-3-O-tert-butyldimethylsilyl-5-benzoyloxymethyl-1,2-O-cyclohexylidene-4-cyclohexen-1,2,3-triol 
• 176198-55-3 Benzoic acid (1R,4R,7S,8S)-7-acetoxy-8-hydroxy-2,3-dioxa-bicyclo[2.2.2]oct-5-en-1-ylmethyl ester 
• 175979-28-9 (1R,2R,3S,4S,5S)-4-O-acetyl-5-(benzoyloxymethyl)-3-O-(tert-butyldimethylsilyl)-1,2-O-cyclohexylidenecyclohexane-1,2,3,4,5-pentol 
• 175979-30-3 Benzoic acid (5R,6R)-6-acetoxy-5-(tert-butyl-dimethyl-silanyloxy)-cyclohexa-1,3-dienylmethyl ester 
• 203317-81-1 (1R,2R,3S)-5-(benzoyloxymethyl)-1,2-O-cyclohexylidene-4-cyclohexene-1,2,3-triol 

Relevant academic research and scientific papers

Enantiospecific syntheses of (+)-crotepoxide, (+)-boesenoxide, (+)-β- senepoxide, (+)-pipoxide acetate, (-)-iso-crotepoxide, (-)-senepoxide, and (- )-tingtanoxide from (-)-quinic acid

A convenient strategy that is ideally suited for the Construction of all the naturally occurring cyclohexane diepoxides and cyclohexene epoxides is described. The key intermediate 12, a 1,3-cyclohexadiene, has been prepared from (-)-quinic acid in 11 steps with 18% overall yield: Singlet oxygen photooxygenation of the 1,3-cyclohexadiene followed by rearrangement of the resultant endoperoxides with either cobalt-meso-tetraphenylporphyrin or trimethyl phosphite afforded enantiopure (+)-crotepoxide, (+)-boesenoxide, and (-)-iso-crotepoxide or (-)-senepoxide, (+)-β-senepoxide, (+)-pipoxide acetate, and (-)-tingtanoxide, respectively.

STUCTURES OF β-SENEPOXIDE, TINGTANOXIDE, AND THEIR DIENE PRECURSORS. CONSTITUENTS OF UVARIA FERRUGINEA.

β-Senepoxide 9, Tingtanoxide 10, and their diene precursors 7 and 8 were isolated from Uvaria ferruginea (Annonaceae).Their structures and absolute configurations were reduced using spectroscopy and chemical correlations with compounds of known stereostru