86743-49-9Relevant academic research and scientific papers
OBSERVATION AND EVALUATION OF THE SYNCHRONOUS LIGAND ATOM PYRAMIDAL INVERSIONS IN BINUCLEAR RHENIUM CARBONYL HALIDE COMPLEXES OF DISULPHIDES AND DISELENIDES: AN X-RAY CRYSTAL STRUCTURE OF
Abel, Edward W.,Bhargava, Suresh K.,Bhatti, Maqbool M.,Mazid, Muhammed A.,Orrell, Keith G.,et al.
, p. 373 - 382 (1983)
The dinuclear complexes (X = Cl or Br, R = Ph or Me3Si, E = S or Se) have been prepared and characterized.A variable temperature 1H NMR study on these complexes demonstrated the pyramidal atomic inversion process at the coordinated sulphur and selenium atoms.Total band-shape fittings were used to yield activation parameters for the rate process, in which the two sulphur or selenium atoms undergo synchronous or correlated inversion.
