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CAS

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86747-89-9

dihydrido(carbonato)(diphenylacetylene)tris(triisopropylphosphine)rhodium(III) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 86747-89-9 Structure

  • Basic information

    1. Product Name: dihydrido(carbonato)(diphenylacetylene)tris(triisopropylphosphine)rhodium(III)
    2. Synonyms: dihydrido(carbonato)(diphenylacetylene)tris(triisopropylphosphine)rhodium(III)
    3. CAS NO:86747-89-9
    4. Molecular Formula:
    5. Molecular Weight: 926.788
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 86747-89-9.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: dihydrido(carbonato)(diphenylacetylene)tris(triisopropylphosphine)rhodium(III)(CAS DataBase Reference)
    10. NIST Chemistry Reference: dihydrido(carbonato)(diphenylacetylene)tris(triisopropylphosphine)rhodium(III)(86747-89-9)
    11. EPA Substance Registry System: dihydrido(carbonato)(diphenylacetylene)tris(triisopropylphosphine)rhodium(III)(86747-89-9)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 86747-89-9(Hazardous Substances Data)

86747-89-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 86747-89-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,6,7,4 and 7 respectively; the second part has 2 digits, 8 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 86747-89:
(7*8)+(6*6)+(5*7)+(4*4)+(3*7)+(2*8)+(1*9)=189
189 % 10 = 9
So 86747-89-9 is a valid CAS Registry Number.

86747-89-9Relevant articles and documents

Reactions of Dihydrido(bicarbonato)bis(triisopropylphosphine)rhodium(III) with Alkynes. Formation of Rh2H2(O2CO)(PhCCPh)(P(i-Pr)3)3 and the Stereoselective Hydrogenation of Alkynes to Trans Olefins

Yoshida, T.,Youngs, Wiley J.,Sakaeda, T.,Ueda, T.,Otsuka, S.,Ibers, James A.

, p. 6273 - 6278 (1983)

A recation of RhH2(O2COH)(P(i-Pr)3)2 (1) with PhCCPh has been found to give trans-stilbene and a novel binuclear rhodium complex Rh2H2(O2CO)(PhCCPh)(P(i-Pr)3)3 (2).A similar reaction with MeO2CCCCO2Me results both in H2 evolution and half-hydrogenation, while with F3CCCCF3 only H2 evolution is observed.Compound 1 catalyzes the stereoselective half-hydrogenation of alkynes to trans olefins.Complex 2 crystallizes in the monoclinic space group C52h-P21/c, with four formula units in a cell of dimensions a = 17.158 (4) Angstroem, b = 23.916 (3) Angstroem, c = 11.255 (3) Angstroem, β = 103.3 (1) deg, and V = 4494 Angstroem3 (t ca. -160 deg C).In the solid state 2 consists of a distorted octahedral Rh(III) center and a distorted square-planar Rh(I) center bridged by a bis-bidentate carbonato group.

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