86767-65-9Relevant academic research and scientific papers
Synthesis and characterization of hexakis(alkyl isocyanide) and hexakis(aryl isocyanide) complexes of technetium(I)
Abrams, Michael J.,Davison, Alan,Jones, Alun G.,Costello, Catherine E.,Pang, Henrianna
, p. 2798 - 2800 (2008/10/08)
The complexes [Tc(CNR)6]PF6 (where R = tert-butyl, methyl, cyclohexyl, and phenyl) have been prepared by reduction of the pertechnetate ion with aqueous Na2S2O4 in the presence of the isocyanide ligands. These complexes have been characterized by elemental analysis, optical, infrared, and 1H NMR spectroscopy, conductance, cyclic voltammetry, and field desorption mass spectrometry.
