86769-69-9Relevant academic research and scientific papers
PALLADIUM-CATALYZED ALLYLATION OF α-ISOCYANOCARBOXYLATES
Ito, Yoshihiko,Sawamura, Masaya,Matsuoka, Masato,Matsumoto, Yonetatsu,Hayashi, Tamio
, p. 4849 - 4852 (2007/10/02)
α-Isocyanocarboxylates underwent palladium-catalyzed allylation with allylic acetates, in which Π-allylpalladium(II)intermediate was involved.The catalytic allylation of methyl α-isocyano(phenyl)acetate using an optically active ferrocenylphosphine ligand
O-SILYLATED ENOLATES IN ORGANIC SYNTHESIS: SULPHUR-MEDIATED ALKYLATION OF ESTERS WITH ALKENES.
Patel, Shailesh K.,Paterson, Ian
, p. 1315 - 1318 (2007/10/02)
O-Silylated ester enolates can be alkylated, under ZnBr2-catalysis, by the PhSCl-adducts of mono- and di-substituted alkenes to give γ-phenylthioesters, from which sulphur can be removed both reductively and oxidatively.This alkene carbosulphenylation rea
