86795-39-3

Basic information

• Product Name: (2S,3R,4R,5S,6S)-3,4,5-tris(benzyloxy)-2-chloro-6-methyltetrahydro-2H-pyran
• Synonyms: (2S,3R,4R,5S,6S)-3,4,5-tris(benzyloxy)-2-chloro-6-methyltetrahydro-2H-pyran
• CAS NO: 86795-39-3
• Molecular Weight: 452.978
• Mol File: 86795-39-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (2S,3R,4R,5S,6S)-3,4,5-tris(benzyloxy)-2-chloro-6-methyltetrahydro-2H-pyran(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R,4R,5S,6S)-3,4,5-tris(benzyloxy)-2-chloro-6-methyltetrahydro-2H-pyran(86795-39-3)
• EPA Substance Registry System: (2S,3R,4R,5S,6S)-3,4,5-tris(benzyloxy)-2-chloro-6-methyltetrahydro-2H-pyran(86795-39-3)

Safety Data

• Hazardous Substances Data: 86795-39-3(Hazardous Substances Data)

Upstream product

• 6014-42-2 L-rhamnose 
• 64650-81-3 allyl α-L-rhamnopyranoside 
• 197916-07-7 2-allyloxy-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran 
• 210426-02-1 2,3,4-tri-O-benzyl-L-rhamnopyranose 
• 475672-25-4 allyl L-rhamnopyranoside 
• 73-34-7 L-rhamnose 
• 86795-38-2 2,3,4-tri-O-(phenylmethyl)-α-L-rhamnopyranoside 

Downstream Products

• 129815-49-2 (2R,3R,4R,5S,6S)-3,4,5-Tris-benzyloxy-2-decyloxy-6-methyl-tetrahydro-pyran 
• 129796-78-7 (2S,3R,4R,5S,6S)-3,4,5-Tris-benzyloxy-2-decyloxy-6-methyl-tetrahydro-pyran 
• 129796-69-6 3β-cholestanyl 2,3,4-tri-O-benzyl-α-L-rhamnopyranoside 
• 129796-70-9 3β-cholestanyl 2,3,4-tri-O-benzyl-β-L-rhamnopyranoside 
• 86795-41-7 p-aminophenyl 2-O-acetyl-3-O-α-L-rhamnopyranosyl-α-L-rhamnopyranoside 
• 160962-42-5 C₈₁H₁₀₀O₁₂ 
• 160848-32-8 C₈₀H₉₆O₁₂ 
• 120269-13-8 O-(2,3,4-tri-O-benzyl-α-L-rhamnopyranosyl)-(1->1)-2,3,4-tri-O-benzyl-α-L-rhamnopyranoside 
• 86795-40-6 p-nitrophenyl 2-O-acetyl-4-O-benzyl-3-O-(2,3,4-tri-O-benzyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranoside 
• 127084-95-1 C₅₇H₆₂O₁₀ 

Relevant articles and documents

Highly regioselective and stereoselective synthesis of C-Aryl glycosidesvianickel-catalyzedortho-C-H glycosylation of 8-aminoquinoline benzamides

C-Aryl glycosides are of high value as drug candidates. Here a novel and cost-effective nickel catalyzedortho-CAr-H glycosylation reaction with high regioselectivity and excellent α-selectivity is described. This method shows great functional group compatibility with various glycosides, showing its synthetic potential. Mechanistic studies indicate that C-H activation could be the rate-determining step.

Solvent-free synthesis of glycosyl chlorides based on the triphenyl phosphine/hexachloroacetone system

Glycosyl chlorides, useful as glycosyl donors in glycoside synthesis and precursors in organic synthesis, can be easily prepared under solvent-free conditions by exposing a sugar hemiacetal to an equimolar mixture of PPh3 and hexachloroacetone