83916-89-6Relevant academic research and scientific papers
Mannose-binding geometry of pradimicin A
Nakagawa, Yu,Doi, Takashi,Taketani, Takara,Takegoshi,Igarashi, Yasuhiro,Ito, Yukishige
, p. 10516 - 10525 (2013/08/23)
Pradimicins (PRMs) and benanomicins are the only family of non-peptidic natural products with lectin-like properties, that is, they recognize D-mannopyranoside (Man) in the presence of Ca2+ ions. Coupled with their unique Man binding ability, t
β-Rhamnosides from 6-thio mannosides
Christina, Alphert E.,Es, Daan Van Der,Dinkelaar, Jasper,Overkleeft, Hermen S.,Marel, Gijsbert A. Van Der,Codee, Jeroen D. C.
supporting information; experimental part, p. 2686 - 2688 (2012/04/10)
Upon condensation of 6-thio-6-deoxy-mannosyl donors 1,2-cis products are obtained with a high degree of stereoselectivity. Subsequent reductive removal of the 6-thio functionality gives 1,2-cis rhamnosides. The 1,2-cis-selectivity can be rationalized with
α-Selective thermal glycosidation of rhamnosyl and mannosyl chlorides
Nishizawa, Mugio,Kan, Yukiko,Shimomoto, Waka,Yamada, Hidetoshi
, p. 2431 - 2434 (2007/10/02)
Stereoselective thermal glycosylation of a variety of alcohols with 2,3,4-tri-O-benzylα-L-rhamnopyranosyl chloride and 2,3,4,6-tstra-O-benzyl-α-D-mannopyranosyl chloride have achieved to give α-glycosides in high selectivity.
SYNTHESIS OF (1->1)-BONDED RHAMNOPYRANOSYL-RHAMNOPYRANOSIDES CONTAINING L,L AND L,D BUILDING-STONES. HIGH-FIELD 1H- AND 13C-NMR SPECTROSCOPIC STUDIES ON THE CONFORMATION OF THE INTERGLYCOSIDIC BONDS
Liptak, A.,Goendoer, A.
, p. 309 - 322 (2007/10/02)
Rhamnosylation of 2,3,4-tri-O-acetyl-L- (1) and 2,3,4-tri-O-benzyl-D-rhamnopyranose (9) with α-acetobromo-L-rhamnose resulted in fully protected α-L, α-L-, α-L, β-L-, α-D,α-L-, and β-D,α-L-rhamnopyranosyl-rhamnopyranosides.The signal of the anomeric carbo
