86806-91-9Relevant academic research and scientific papers
The crystal structure of 1-p-bromophenylsilatrane at 293 K and 133 K
Parkanyi,Kertesz,Bihatsi,Hencsei
, p. 153 - 158 (1996)
The crystal structure of 1-p-bromophenylsilatrane was determined at ambient and low temperature. The methylene groups of the silatrane skeleton in the β-position to the nitrogen atom are disordered in the ambient temperature structure. The disorder disappears at 133 K. The Si mutually implies N dative bond length is nearly identical at both temperatures (2.139(3) and 2.132(2) A). The deviation of the atoms in the silatrane moiety from the ideal three-fold symmetry seems to point to the most dynamically behaving parts of the molecule.
Organosilatrane building blocks
Brennan, Bradley J.,Gust, Devens,Brudvig, Gary W.
, p. 1062 - 1064 (2014/02/14)
Phenylsilatrane analogues containing reactive amino, bromo, boronic ester, and alkynyl functional groups for coupling reactions have been prepared. Pinacol boronic ester and ethynyl analogues were synthesized from 4- bromophenylsilatrane by palladium cata
Organosilatrane building blocks
Brennan, Bradley J.,Gust, Devens,Brudvig, Gary W.
, p. 1062 - 1064 (2015/02/19)
Phenylsilatrane analogues containing reactive amino, bromo, boronic ester, and alkynyl functional groups for coupling reactions have been prepared. Pinacol boronic ester and ethynyl analogues were synthesized from 4-bromophenylsilatrane by palladium catal
Synthesis of organosilatranes via rhodium(I)-catalyzed silylation of organic iodides with hydrosilatrane
Murata, Miki,Yamasaki, Hiroyuki,Uogishi, Kota,Watanabe, Shinji,Masuda, Yuzuru
, p. 2944 - 2946 (2008/03/13)
The silylation of aryl and alkenyl iodides with hydrosilatrane in the presence of a rhodium(I) catalyst and DABCO provides the corresponding organosilatranes in good yield. The same catalyst system also enables the related coupling of hydrogermatrane. Georg Thieme Verlag Stuttgart.
