868070-20-6

Basic information

• Product Name: Silane, [(1-methoxy-2-methyl-1-propenyl)oxy]tris(1-methylethyl)-
• CAS NO: 868070-20-6
• Molecular Formula: C14H30O2Si
• Molecular Weight: 258.476
• Mol File: 868070-20-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, [(1-methoxy-2-methyl-1-propenyl)oxy]tris(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [(1-methoxy-2-methyl-1-propenyl)oxy]tris(1-methylethyl)-(868070-20-6)
• EPA Substance Registry System: Silane, [(1-methoxy-2-methyl-1-propenyl)oxy]tris(1-methylethyl)-(868070-20-6)

Safety Data

• Hazardous Substances Data: 868070-20-6(Hazardous Substances Data)

Upstream product

• 547-63-7 Methyl isobutyrate 
• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 

Downstream Products

• 38661-07-3 trans-4-Methyl-6-phenyl-3-cyclohexencarbonsaeuremethylester 
• 101499-38-1 dimethyl 2,2-dimethyl-3-phenylpentane-1,5-dioate 
• 108774-33-0 3,4-dimethyl-6t-phenyl-cyclohex-3-ene-r-carboxylic acid methyl ester 

Relevant articles and documents

Synthesis, resolution, and aldol reactions of a planar-chiral Lewis acid complex

The synthesis and resolution of a new planar-chiral Lewis acid complex is described. The compound is applied to asymmetric Mukaiyama aldol reactions, leading to the formation of the desired product with good stereoselectivity. The sense of stereoselection is as predicted by the design, which exploits the ability of the Lewis acid to simultaneously serve as a σ and a π acceptor. Mechanistic observations are consistent with rate-determining formation of an aldehyde-Lewis acid complex, followed by rapid nucleophilic addition. Copyright