86808-52-8

Upstream product

• 98627-69-1 1,3-diaminoxypropane 
• 1761-61-1 5-bromosalicyclaldehyde 
• 120-70-7 N,N'-propane-1,3-diylbis(salicylideneimine) 

Downstream Products

• 192586-87-1 Mn⁽³⁺⁾*C₁₇H₁₄Br₂N₂O₂^(2-)*O₂CC₂H₅^(1-) = [Mn(C₁₇H₁₄Br₂N₂O₂)(O₂CC₂H₅)] 
• 192586-93-9 Mn⁽³⁺⁾*C₁₇H₁₄Br₂N₂O₂^(2-)*O₂CC₆H₅^(1-)*H₂O = [Mn(C₁₇H₁₄Br₂N₂O₂)(O₂CC₆H₅)]*H₂O 
• 192586-95-1 Mn⁽³⁺⁾*C₁₇H₁₄Br₂N₂O₂^(2-)*O₂CCH₂C₆H₅^(1-) = [Mn(C₁₇H₁₄Br₂N₂O₂)(O₂CCH₂C₆H₅)] 
• 192586-89-3 Mn⁽³⁺⁾*C₁₇H₁₄Br₂N₂O₂^(2-)*O₂CC₃H₇^(1-) = [Mn(C₁₇H₁₄Br₂N₂O₂)(O₂CC₃H₇)] 
• 192586-91-7 Mn⁽³⁺⁾*C₁₇H₁₄Br₂N₂O₂^(2-)*O₂CC₄H₉^(1-) = [Mn(C₁₇H₁₄Br₂N₂O₂)(O₂CC₄H₉)] 
• 192586-85-9 Mn⁽³⁺⁾*C₁₇H₁₄Br₂N₂O₂^(2-)*O₂CCH₃^(1-) = [Mn(C₁₇H₁₄Br₂N₂O₂)(O₂CCH₃)] 

Relevant academic research and scientific papers

Selective copper-mediated halogenation of aromatic rings under mild conditions

A mild copper-mediated halogenation reaction of phenolic rings is reported. The reaction of bis(2-hydroxybenzyl)-1,3-diaminopropane (H2bhbd) with copper(II) chloride in acetonitrile generates linear trinuclear [Cu 3(bhcbd)2Cl2](CH3CN), containing modified ligands, whose phenol moieties are selectively chlorinated at the 5-position. Under comparable experimental conditions with copper(II) bromide, bromination of the ligand is observed, albeit at a slower reaction rate. In the presence of trialkylorthoformates, which are used as dehydrating agents, a ring closure of the ligand is observed after removal of copper to yield a product with a six-membered ring. This product has been isolated and characterized by NMR spectroscopy and MS. Similarly, bromination of bis(2-hydroxybenzyl)-1,3- diiminopropane (H2bhbdi) occurs in the presence of copper(II) bromide, with concomitant formation of a linear trinuclear complex. Surprisingly, an asymmetric dinuclear copper(II) coordination compound without chlorination of the ligand is obtained when the related ligand bis(2-hydroxybenzyl)-1,3-diminopropane (H2bhbdi) reacts with copper(II) chloride. Copyright