98627-69-1

Basic information

• Product Name: Hydroxylamine, O,O'-1,3-propanediylbis-
• Synonyms: O,O'-propane-1,3-diyl-bis-hydroxylamine;hydroxylamine-O-[3-(aminooxy)propyl];1.3-Bis-aminooxy-propan;Hydroxylamine,O,O'-1,3-propanediylbis;1,3-bis-aminooxy-propane;1,3-diaminoxypropane
• CAS NO: 98627-69-1
• Molecular Formula: C3H10N2O2
• Molecular Weight: 106.125
• Mol File: 98627-69-1.mol

Chemical Properties

• CAS DataBase Reference: Hydroxylamine, O,O'-1,3-propanediylbis-(CAS DataBase Reference)
• NIST Chemistry Reference: Hydroxylamine, O,O'-1,3-propanediylbis-(98627-69-1)
• EPA Substance Registry System: Hydroxylamine, O,O'-1,3-propanediylbis-(98627-69-1)

Safety Data

• Hazardous Substances Data: 98627-69-1(Hazardous Substances Data)

Usage

Uses

Used in Chemical Synthesis:
Hydroxylamine, O,O'-1,3-propanediylbisis used as a reagent in chemical synthesis for forming oxime and hydroxylamine linkages with aldehydes. Its high reactivity and sensitivity make it suitable for immediate use in various chemical reactions.
Used in Pharmaceutical Industry:
Hydroxylamine, O,O'-1,3-propanediylbisis used as a building block in the synthesis of pharmaceutical compounds. Its ability to form oxime and hydroxylamine linkages allows for the creation of diverse molecular structures with potential therapeutic applications.
Used in Research and Development:
Hydroxylamine, O,O'-1,3-propanediylbisis used as a research tool in the development of new chemical reactions and synthetic pathways. Its unique reactivity and sensitivity make it valuable for studying the mechanisms of various chemical processes and for exploring new methods of chemical synthesis.

Upstream product

• 94212-54-1 1,3-bis(phthalimidooxy)propane 
• 524-38-9 N-hydroxyphthalimide 
• 6674-22-2 1,8-diazabicyclo[5.4.0]undec-7-ene 
• 109-64-8 1,3-dibromo-propane 

Downstream Products

• 1244021-76-8 1,3-bis{[(Z)-(3-methyl-5-oxo-1-phenyl-1H-pyrazolidin-4(4H)-yl)(phenyl)]methyleneaminooxy}propane 
• 1255144-44-5 3,3'-dimethoxy-2,2'-[(1,3-propylene)dioxybis(nitrilomethylidyne)]diphenol 
• 1130479-24-1 4,4'-dichloro-2,2'-[(1,3-propylene)dioxybis(nitrilomethylidyne)]diphenol 
• 86808-52-8 N,N′-bis(5-bromosalicylidenimino)-1,3-diaminopropane 

Relevant articles and documents

Four new nickel(II) complexes based on an asymmetric Salamo-type ligand: Synthesis, structure, solvent effect and electrochemical property

Four new solvent-induced Ni(II) complexes with chemical formulae {[NiL(MeOH)(μ-OAc)]2Ni}·2MeOH (1), {[NiL(EtOH)(μ-OAc)]2Ni} (2), {[NiL(i-PrOH)(μ-OAc)]2Ni} (3) and {[NiL(DMF)(μ-OAc)]2Ni}·2DMF·0.44H2O (4), where H2L = 5-methoxy-4′-chloro-2,2′-[(1,3-propylene)dioxybis(nitrilomethylidyne)]diphenol, have been synthesized and characterized by elemental analyses, 1H NMR, FT-IR, UV-Vis spectra and X-ray crystallography. X-ray crystallographic analyses of the Ni(II) complexes reveal that they crystallize in the triclinic system, space group P1ˉ, and consists of three Ni(II) ions, two deprotonated L2- units, two μ-acetato ligands and two coordinated solvent molecules. In each of the Ni(II) complexes, the Ni(II) ions are hexa-coordinated with a slightly distorted octahedral coordination geometries. Although the molecule structures of the Ni(II) complexes are similar each other, obtained in different solvents, the supramolecular structures are entirely different. The complexes 1 and 3 possess a self-assembled infinite 2D and 1D supramolecular structures via the intermolecular hydrogen bonds, respectively. But the Ni(II) complexes 2 and 4 are formed 0D structures by intramolecular hydrogen bonds. Cyclic voltammetry is used to characterize electrochemical property of the Ni(II) complex 1.

Structurally characterized homotrinuclear Salamo-type nickel(II) complexes: Synthesis, solvent effect and fluorescence properties

Four new solvent-induced Ni(II) complexes with chemical formulae [{NiL(μ2-OAc)(MeOH)}2Ni]·2MeOH (1), [{NiL(μ2-OAc)}2(n-PrOH)(H2O)Ni]·n-PrOH (2), [{NiL(μ2-OAc)(DMF)}2Ni] (3) and [{NiL(μ2-OAc)(DMSO)}2Ni]·2DMSO (4), (H2L?=?4-Nitro-4′-chloro-2,2′-[(1,3-propylene)dioxybis(nitrilomethylidyne)]diphenol) have been synthesized and characterized by elemental analyses, FT-IR, UV–Vis spectra and X-ray crystallography. X-ray crystal structure determinations revealed that each of the Ni(II) complexes 1–4 consists of three Ni(II) atoms, two completely deprotonated (L)2? units, two μ2-acetate ions and two coordinated solvent molecules (solvents are methanol, n-propanol, water, N,N-dimethylformamide and dimethyl sulphoxide, respectively). Although the four complexes 1–4 were synthesized in different solvents, it is worthwhile that the Ni(II) atoms in the four complexes 1–4 adopt hexa–coordinated with slightly distorted octahedral coordination geometries, and the ratios of the ligand H2L to Ni(II) atoms are all 2: 3. The complexes 1–4 possess self-assembled infinite 1D, 3D, 1D and 2D supramolecular structures via the intermolecular hydrogen bonds, respectively. In addition, fluorescence behaviors were investigated in the complexes 1–4.

Synthesis and characterization of mononuclear copper (II) complex with 5,5'-dihydroxy-2,2'-[1,1'-(propane-1,3-diyldioxydinitrilo)dimethylidyne]diphenol

Copper(II) complex [Cu(H2L)]·CH3CH 2OH·0.5H2O has been synthesized by the reaction of copper(II) acetate monohydrate with 5,5'- dihydroxy-2,2'-[1,1'-(propane-1,3- diyldioxydinitrilo)dimethylidyne]diphenol in anh

Dimethylsulfoxide-induced trinuclear Co(II) and Ni(II) salamo-type complexes: Syntheses, crystal structures and spectral properties

Two homotrinuclear Co(II) and Ni(II) complexes, [{CoL(OAc)(DMSO)}2Co]·2DMSO and [{NiL(OAc)(DMSO)}2Ni] have been synthesized by the reaction of 4,4′-dichloro-2,2′-[(1,3-propylene)dioxybis(nitrilomethylidyne)]diphenol (H2L) with cobalt(II) and nickel(II) acetate tetrahydrate in the solution of DMSO, respectively, and characterized by elemental analyses, IR, UV–Vis spectra and X-ray crystallography. In the Co(II) complex, terminal Co2 and Co2#1 atoms located in the N2O2 sites, and are both hexa-coordinated with slightly distorted octahedral geometries. While the central Co1 atom is also hexa-coordinated by six oxygen atoms, four are phenoxy oxygen atoms from two (L)2? units, and two oxygen atoms from μ2-acetate ions, which has formed a octahedral geometry. In the Ni(II) complex, coordination environments of the Ni(II) atoms are similar to those of the Co(II) atoms. Infinite 1D supramolecular structure is formed via abundant intermolecular hydrogen bonding interactions in the Co(II) complex.

Synthesis and structural characterization of trinuclear Cu2+, Zn2+ and Zn2+-Eu3+ complexes based on 2,3-dihydroxybenzene-1,4-dicarbaldehyde, 1,3-bis(Aminooxy)propane with 3-ethoxysalicylaldehyde

A novel bis(salamo)-type multipledentate chelating ligand H4L and its three Cu2+, Zn2+ and Zn2+-Eu3+ complexes have been designed and synthesized and characterized by elemental analyses, IR, UV-visibl

Synthesis and structural characterization of bromo-substituted salamo-type bisoximes based on bis(aminooxy)alkane and 3,5-dibromosalicylaldehyde

A series of bromo-substituted Salamo-type bisoximes H2L1-H2L3 have been synthesized through condensation reactions of 3,5-dibromosalicylaldehyde with 1,2-bis(aminooxy)ethane, 1,3-bis(aminooxy)propane and 1,4-bis

Synthesis and characterization of Salamo-type bisoximes based on 3-ethoxysalicyladehyde and Bis(aminooxy)alkane

A series of ethoxy-substituted Salamo-type bisoximes H2L1-H2L4 have been synthesized from 3-ethoxysalicyladehyde and 1,3-bis(aminooxy)propane, 1,4- bis(aminooxy)butane, 1,5-bis(aminooxy)pentane or 1,6-bis(aminoo

Synthesis and characterization of methoxy-substituted salamo-type bisoximes based on bis(aminooxy)alkane and 3-methoxy-2-hydroxybenzaldehyde

Four new methoxy-substituted Salamo-type bisoxime compounds 6,6'-dimethoxy-2,2'-[(propylene-1,3-diyldioxy)bis(nitrilomethylidyne)] diphenol (H2L1), 6,6'-dimethoxy-2,2'-[(butylene-1,4-diyldioxy)bis(nitrilomethylidyne)]diphenol (H2L2), 6,6'-dimethoxy- 2,2'-[(propane-1,5-diyldioxy)bis(nitrilome-thylidyne)]diphenol (H2L3) and 6,6'-dimethoxy-2,2'-[(hexane-1,6-diyldioxy)bis(nitrilomethylidyne)] diphenol (H2L4) have been synthesized through condensation reactions under hot ethanol medium, respectively and characterized by elemental analyses, IR, UV-visible and 1H NMR spectra.

Synthesis and characterization of multihalogen substituted salamo-type bisoximes

Four tetrahalogen substituted Salamo-type bisoximes H2L1-H2L4 have been synthesized from 3-bromo-5-chloro-2-hydroxybenzaldehyde and 1,3-bis(aminooxy) propane, 1,4-bis(aminooxy)butane, 1,5-bis(aminooxy)pentane or 1,6-bis(aminooxy)hexane in ethanol solution

Synthesis and Characterization of Transition Metal Complexes with 2,2'-[(Propylene-1,3-diyldioxy)bis(nitrilomethylidyne)]diphenol

In anhydrous ethanol medium, a series of transition metal complexes have been synthesized by the reaction of 2,2'-[(propylene-1,3- diyldioxy) bis(nitrilomethylidyne)]diphenol (H2L) with Cu(II), Ni(II), Co(II) and Mn(II) acetate hydrate. All the