86814-76-8

Basic information

• Product Name: 4,9-Dimethyl-6,7-diphenyl-5,8-dioxa-13,14-diazahexacyclo<10.2.2.0^2,11.0^3,10.0^4,6.0^7,9>hexadec-15-en-13,14-dicarbonsaeure-diethylester
• Synonyms: 4,9-Dimethyl-6,7-diphenyl-5,8-dioxa-13,14-diazahexacyclo<10.2.2.0^2,11.0^3,10.0^4,6.0^7,9>hexadec-15-en-13,14-dicarbonsaeure-diethylester
• CAS NO: 86814-76-8
• Molecular Weight: 542.632
• Mol File: 86814-76-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4,9-Dimethyl-6,7-diphenyl-5,8-dioxa-13,14-diazahexacyclo<10.2.2.0^2,11.0^3,10.0^4,6.0^7,9>hexadec-15-en-13,14-dicarbonsaeure-diethylester(CAS DataBase Reference)
• NIST Chemistry Reference: 4,9-Dimethyl-6,7-diphenyl-5,8-dioxa-13,14-diazahexacyclo<10.2.2.0^2,11.0^3,10.0^4,6.0^7,9>hexadec-15-en-13,14-dicarbonsaeure-diethylester(86814-76-8)
• EPA Substance Registry System: 4,9-Dimethyl-6,7-diphenyl-5,8-dioxa-13,14-diazahexacyclo<10.2.2.0^2,11.0^3,10.0^4,6.0^7,9>hexadec-15-en-13,14-dicarbonsaeure-diethylester(86814-76-8)

Safety Data

• Hazardous Substances Data: 86814-76-8(Hazardous Substances Data)

Upstream product

• 24009-91-4 (1R,2R,5S,6S)-7,8-Diaza-tricyclo[4.2.2.0^2,5]deca-3,9-diene-7,8-dicarboxylic acid diethyl ester 
• 73240-57-0 4,7-Dimethyl-15-oxo-5,6-diphenyl-11,12-diazapentacyclo<8.2.2.1^4,7.0^2,9.0^3,8>pentadeca-5,13-dien-11,12-dicarbonsaeure-diethylester 
• 86814-77-9 4,7-Dimethyl-5,6-diphenyl-11,12-diazatetracyclo<8.2.2.0^2,9.0^3,8>tetradeca-4,6,13-trien-11,12-dicarbonsaeure-diethylester 

Relevant articles and documents

Attempts to Synthesize Derivatives of the 2,3-Diazabicycloocta-5,7-diene System

The 2,3-diazabicycloocta-5,7-diene derivatives 1a and b could neither be obtained by a photoaromatization reaction of 8 nor by an electrolytic oxidation of the dicarboxylic acids 13a,b.Cycloadditions to 21 lead to derivatives of the title system.At temperatures above -10 deg C these undergo a -cycloreversion to produce the tetrahydrophthalazines 22.The thermal transformation of 21 to 22 is rationalized on the basis of a chain mechanism.