868161-65-3Relevant academic research and scientific papers
Stereoselective total synthesis of palmyrolide A via intramolecular trans N-methyl enamide formation
Borra, Suresh,Amrutapu, Sravanth Kumar,Pabbaraja, Srihari,Singh, Yadav Jhillu
supporting information, p. 4456 - 4459 (2016/09/14)
The stereoselective total synthesis of palmyrolide A was accomplished through macrocyclization reaction involving trans enamide formation by coupling of vinyl iodide with secondary amide in an intramolecular fashion. The two coupling partners, vinyl iodide 4 and secondary amide 3 were synthesized from the same intermediate alcohol 5. Yamaguchi esterification and CBS-reduction are the other key steps involved in the synthesis.
Enantioselective total synthesis and determination of the absolute configuration of the 4,6,8,10,16,18-hexamethyldocosane from Antitrogus parvulus
Herber, Christian,Breit, Bernhard
, p. 3512 - 3519 (2008/02/12)
The absolute and relative configuration of the hexamethyldocosane (1) isolated from the cuticula of Antitrogus parvulus was determined based on the total synthesis of both diastereomers 1a and 1b in enantiomerically pure form. The synthesis demonstrates t
Enantioselective total synthesis and determination of the absolute configuration of the 4,6,8,10,16,18-hexamethyldocosane from Antitrogus parvulus
Herber, Christian,Breit, Bernhard
, p. 5267 - 5269 (2007/10/03)
(Chemical Equation Presented) A copper-catalyzed sp3-sp 3 cross-coupling for fragment coupling in a total synthesis is demonstrated. The diastereo- and enantioselective total synthesis of the 4,6,8,10,16,18-hexamethyldocosanes highli
