1158076-88-0Relevant academic research and scientific papers
Stereoselective total synthesis of putaminoxin
Yadav, Jhillu Singh,Raju, Ande,Ravindar, Kontham,Reddy, Basi V. Subba,Khazim Al Ghamdi, Ahmad Al
experimental part, p. 585 - 590 (2012/04/04)
The stereoselective total synthesis of a phytotoxic macrolide putaminoxin, isolated from the culture of Phoma putaminum fungus, has been accomplished by utilization of Sharpless asymmetric epoxidation, Birch reduction, Jacobsens kinetic resolution of race
A practical total synthesis of (+)-spirolaxine methyl ether
Yadav,Sreenivas,Srinivas Reddy,Subba Reddy
supporting information; experimental part, p. 8307 - 8310 (2011/02/27)
An efficient and practical total synthesis of (+)-spirolaxine methyl ether is described. The phthalide-aldehyde 3 has been prepared via the Diels-Alder reaction between 1,4-unconjugated diene 5 and a long-chain acetylenic dienophile 6. The carbon framework of spiroketal sulfone 4 has been constructed from monobenzyl protected 1,5-pentanediol and the stereochemistry in both the phthalide portion and the spiroketal portion has been established by the Sharpless asymmetric epoxidation.
