868162-64-5

Upstream product

• 68602-57-3 trifluoroacetyl triflate 
• 404574-43-2 3β-acetoxy-12β-benzoyloxy-5α-furostan-14,26-diene 

Downstream Products

• 868162-82-7 Benzoic acid (3S,5S,8R,9S,10S,12R,13S)-3-acetoxy-17-[(1S,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1,5-dimethyl-hex-5-enyl]-10,13-dimethyl-2,3,4,5,6,7,8,9,10,11,12,13-dodecahydro-1H-cyclopenta[a]phenanthren-12-yl ester 
• 868162-88-3 C₄₁H₅₆O₈ 
• 868162-84-9 Benzoic acid (3S,5S,8R,9S,10S,12R,13S)-3-acetoxy-17-{(S)-1-[5,5-dibromo-2-(3-methyl-but-3-enyl)-[1,3]dioxan-2-yl]-ethyl}-10,13-dimethyl-2,3,4,5,6,7,8,9,10,11,12,13-dodecahydro-1H-cyclopenta[a]phenanthren-12-yl ester 
• 868162-85-0 Benzoic acid (3S,5S,8R,9S,10S,12R,13S)-3-acetoxy-17-{(S)-1-[5,5-dimethyl-2-(3-methyl-but-3-enyl)-[1,3]dioxan-2-yl]-ethyl}-10,13-dimethyl-2,3,4,5,6,7,8,9,10,11,12,13-dodecahydro-1H-cyclopenta[a]phenanthren-12-yl ester 
• 868162-65-6 Benzoic acid (3S,5S,8R,9S,10S,12R,13S)-3-acetoxy-10,13-dimethyl-17-{(S)-1-[2-(3-methyl-but-3-enyl)-[1,3]dioxan-2-yl]-ethyl}-2,3,4,5,6,7,8,9,10,11,12,13-dodecahydro-1H-cyclopenta[a]phenanthren-12-yl ester 
• 868162-83-8 Benzoic acid (3S,5S,8R,9S,10S,12R,13S)-3-acetoxy-17-((S)-1,5-dimethyl-2-oxo-hex-5-enyl)-10,13-dimethyl-2,3,4,5,6,7,8,9,10,11,12,13-dodecahydro-1H-cyclopenta[a]phenanthren-12-yl ester 
• 868162-81-6 3β-acetoxy-12b-benzoyloxy-22-hydroxy-5α-furostan-14,16-diene 

Relevant academic research and scientific papers

Mild isomerative opening of tetrahydrofuranyl subunits in steroids using TFAT (trifluoroacetyl trifluoromethanesulfonate): Application to synthesis of C17-OH rockogenin acetate

A novel and efficient tetrahydrofuranyl ring opening method was developed using the highly reactive TFAT reagent in the presence of an acid scavenger, 2,6-di-tert-butyl-4-methylpyridine. Various acid sensitive groups are compatible with the reaction condi

A biomimetically inspired, efficient synthesis of the south 7 hemisphere of cephalostatin 7

Synthesis of the South 7 hemisphere of cephalostatin 7 is described applying a second-generation synthetic strategy, which retains all the existing carbons in hecogenin acetate 1. TFAT (trifluoroacetyl trifluoromethanesulfonate)-assisted E-ring opening yi