86823-46-3Relevant academic research and scientific papers
Contrasting conformational behavior of 5-methylsulfonyl-1,3-dioxane and -1,3-dithiane in the minimization of steric and electrostatic repulsive interactions
Cruz-Sánchez, J.Samuel,Juaristi, Eusebio
, p. 9369 - 9372 (2002)
The preparation of novel 1,3-dithiane derivatives, cis- and trans-2-tert-butyl-5-methylsulfonyl-1,3-dithiane, was achieved by acid-catalyzed condensation of 2-methylsulfonyl-1,3-propanedithiol with pivalaldehyde. The former dithiol was obtained from allyl
A radical based addition-elimination route for the preparation of indoles
Murphy, John A.,Scott, Karen A.,Sinclair, Rhoha S.,Martin, Concepcion Gonzalez,Kennedy, Alan R.,Lewis, Norman
, p. 2395 - 2408 (2007/10/03)
Indoles, including tricyclic derivatives, are produced by cyclisations of aryl radicals onto vinyl halides followed by elimination of halide radical and tautomerism of the resulting product; the aryl radicals are produced using "clean methodology" either by reaction of iodide ions with arenediazonium salts or by reaction of phosphorus-centred radicals with aryl iodides. The Royal Society of Chemistry 2000.
