868285-52-3

Basic information

• Product Name: [Fe(CH₂SiMe₃)₂(2,6-bis((N-mesityl)acetimidoyl)pyridine)]
• Synonyms: [Fe(CH₂SiMe₃)₂(2,6-bis((N-mesityl)acetimidoyl)pyridine)]
• CAS NO: 868285-52-3
• Molecular Weight: 627.844
• Mol File: 868285-52-3.mol

Chemical Properties

• CAS DataBase Reference: [Fe(CH₂SiMe₃)₂(2,6-bis((N-mesityl)acetimidoyl)pyridine)](CAS DataBase Reference)
• NIST Chemistry Reference: [Fe(CH₂SiMe₃)₂(2,6-bis((N-mesityl)acetimidoyl)pyridine)](868285-52-3)
• EPA Substance Registry System: [Fe(CH₂SiMe₃)₂(2,6-bis((N-mesityl)acetimidoyl)pyridine)](868285-52-3)

Safety Data

• Hazardous Substances Data: 868285-52-3(Hazardous Substances Data)

Upstream product

• 210155-39-8 2,6-bis[1-(2,4,6-trimethylimino)ethyl]pyridine 
• 868285-51-2 [Fe(CH₂SiMe₃)₂(pyridine)₂] 

Downstream Products

• 1581737-35-0 [Fe(CH₂SiMe₃)(^MesBIP)] 
• 1569302-90-4 C₂₉H₃₃F₆FeN₃O₇S₂ 
• 207129-94-0 dichloro(2,6-bis[(2,4,6-trimethylphenylimino)ethyl]pyridine)iron(II) 
• 1569302-89-1 C₃₁H₃₁F₆FeN₃O₄ 

Relevant articles and documents

2,6-diiminopyridine iron(II) dialkyl complexes. Interaction with aluminum alkyls and ethylene polymerization catalysis

Bis(pyridine)iron dialkyl complexes FeR2Py2 (R = CH2Ph, CH2CMe2Ph, and CH2SiMe 3) react with 2,6-diiminopyridine ligands, affording the corresponding organoiron complexes. The complex Fe(CH2SiMe 3)2-(C5H3N-2,6-(C(=N-mesityl)Me)2, 4a, becomes an active ethylene polymerization catalyst upon treatment with Al or Zn alkyls. A catalytically active 1:1 Fe/Al adduct has been detected in solution by 1H and UV-vis spectroscopies.