207129-94-0Relevant academic research and scientific papers
One-Pot, One-Step Precatalysts through Mechanochemistry
Shaw, Thomas E.,Mathivathanan, Logesh,Jurca, Titel
supporting information, p. 4066 - 4070 (2019/11/03)
The development and implementation of transition-metal-based precatalysts have played crucial roles in modern organic synthesis. However, while the use of such species greatly improves sustainability, their preparative routes often rely on multiple time-,
Protonolysis of Fe-C bonds of a diiminopyridineiron(II) dialkyl complex by acids of different strengths: Influence of monoanionic ligands on the spectroscopic properties of diiminopyiridine-FeY2 complexes
ángeles Cartes,Palma, Pilar,Sandoval, John J.,Cámpora, Juan,álvarez, Eleuterio
, p. 73 - 78 (2014/02/14)
The reaction of the dialkyliron complex [Fe(CH2SiMe 3)2(MesBIP)] (MesBIP = 2,6-bis((N-mesityl)acetimidoyl)pyridine) with protic acids (HY) of different strengths (Y = C6F5O, CF3CO2, Cl, CF3SO3) invariably leads to the cleavage of both Fe-C bonds, independent of the Fe/HY ratio used (either 1:2 or 1:1), affording the corresponding complexes [FeY2(MesBIP)]. Relevant spectroscopic features of these compounds, such as paramagnetic 1H NMR shifts and UV-Vis absorption bands, exhibit a marked dependence on the nature of Y.
Heterogenized iron(II) complexes as highly active ethene polymerization catalysts
Schmidt, Roland,Welch, M.Bruce,Palackal, Syriac J,Alt, Helmut G
, p. 155 - 173 (2008/10/08)
The synthesis of new iron(II) diiminopyridine complexes and their heterogenization to give highly active ethene polymerization catalysts is described. The ligands are characterized by 1H NMR, 13C NMR spectroscopy and GC/MS. The compl
Novel olefin polymerization catalysts based on iron and cobalt
Britovsek, George J.P.,Gibson, Vernon C.,Kimberley, Brian S.,Maddox, Peter J.,McTavish, Stuart J.,Solan, Gregory A.,White, Andrew J.P.,Williams, David J.
, p. 849 - 850 (2007/10/03)
A new family of olefin polymerization catalysts, derived from iron and cobalt complexes bearing 2,6-bis(imino)pyridyl ligands, is described.
