868566-32-9

Upstream product

• 36884-28-3 5-phenyl-1-pentanal 
• 814-68-6 acryloyl chloride 
• 942292-90-2 (5S,2E)-5-hydroxy-9-phenylnon-2-ene 
• 1351993-02-6 (S)-methyl 4-hydroxy-8-phenyloctanoate 
• 868566-30-7 (R)-6-[(2S,4S)-2,4-Bis-(4-methoxy-benzyloxy)-8-phenyl-octyl]-5,6-dihydro-pyran-2-one 
• 108-24-7 acetic anhydride 
• 16387-61-4 6-phenylhexanal 
• 1351993-14-0 C₃₄H₅₉NO₄Si₂ 
• 1351993-13-9 C₂₈H₅₂O₃Si₂ 
• 1351993-04-8 C₂₃H₄₀O₄Si 
• 1351993-10-6 (R)-6-((2R,4S)-2,4-bis(tert-butyldimethylsilyloxy)-8-phenyloctyl)-5,6-dihydro-2H-pyran-2-one 
• 1351993-09-3 (4R,6R,8S)-6,8-bis(tert-butyldimethylsilyloxy)-12-phenyldodec-1-en-4-yl acrylate 
• 1351993-08-2 (4R,6R,8S)-6,8-bis(tert-butyldimethylsilyloxy)-12-phenyldodec-1-en-4-ol 
• 1351993-07-1 (5R,7S)-2,2,3,3,9,9,10,10-octamethyl-5-((S)-oxiran-2-ylmethyl)-7-(4-phenylbutyl)-4,8-dioxa-3,9-disilaundecane 

Relevant academic research and scientific papers

Stereocomplementary synthesis of a natural product-derived compound collection on a solid phase

Enantiocomplementary allylation of solid phase-bound aldehydes gives rise to a natural product-derived compound collection, including all stereoisomers of cryptocarya diacetate. The Royal Society of Chemistry 2006.

An organocatalytic route to the synthesis of (6S)-5,6-dihydro-6-[(2R)-2- hydroxy-6-phenylhexyl]-2H-pyran-2-one and ravensara lactones

An organocatalytic enantioselective synthesis of the title compounds has been achieved. The stereogenic centers were generated by the iterative use of proline catalyzed α-aminoxylations and HWE olefination of aldehydes while the lactone ring was construct

Biology-oriented synthesis of stereochemically diverse natural-product- derived compound collections by iterative allylations on a solid support

A strategy aiming at the introduction of stereocenters into polymer-bound natural-product-derived and -inspired compound collections is presented. Treatment of immobilized aldehydes with Brown's pinene-derived allylboranes results in the stereoselective f