868566-32-9Relevant academic research and scientific papers
Stereocomplementary synthesis of a natural product-derived compound collection on a solid phase
Garcia, Ana B.,Lessmann, Torben,Umarye, Jayant D.,Mamane, Victor,Sommer, Stefan,Waldmann, Herbert
, p. 3868 - 3870 (2006)
Enantiocomplementary allylation of solid phase-bound aldehydes gives rise to a natural product-derived compound collection, including all stereoisomers of cryptocarya diacetate. The Royal Society of Chemistry 2006.
An organocatalytic route to the synthesis of (6S)-5,6-dihydro-6-[(2R)-2- hydroxy-6-phenylhexyl]-2H-pyran-2-one and ravensara lactones
Dwivedi, Namrata,Tripathi, Divya,Kumar, Pradeep
, p. 1749 - 1756 (2012/02/03)
An organocatalytic enantioselective synthesis of the title compounds has been achieved. The stereogenic centers were generated by the iterative use of proline catalyzed α-aminoxylations and HWE olefination of aldehydes while the lactone ring was construct
Biology-oriented synthesis of stereochemically diverse natural-product- derived compound collections by iterative allylations on a solid support
Umarye, Jayant D.,Lessmann, Torben,Garcia, Ana B.,Mamane, Victor,Sommer, Stefan,Waldmann, Herbert
, p. 3305 - 3319 (2008/02/10)
A strategy aiming at the introduction of stereocenters into polymer-bound natural-product-derived and -inspired compound collections is presented. Treatment of immobilized aldehydes with Brown's pinene-derived allylboranes results in the stereoselective f
