86857-67-2Relevant academic research and scientific papers
Synthesis of hetero-binuclear derivatives of the tetrathiolato complexes [Mo(η-C5H5CH2SR)2)], R = Prn and Ph, with platinum, palladium, and rhodium
O'hare, Dermot,Green, Malcolm L.H.,Cloke, F.Geoffrey N.
, p. 225 - 231 (2007/10/02)
The compound Mo(η-C5H4(CH2)2SPrn)2(SPrn)2 acts as a bidentate ligand giving the heteronuclear bi-metallic compounds [Mo(η-C5H4CH2CH2SPrn)2-(SPrn)2(PtCl2)],[Mo(η-C5H4CH2CH2SPrn)2(SPrn)2(PdCl2)2], [Mo(η-C5C4CH2CH2SPrn)2(SPrn)2(RhCl3)2], [Mo(η-C5H4CH2CH2SPrn)2(μ-SPrn)2Rh(dppe)]BF4, [Mo(η-C5H4CH2CH2SPrn)2(μ-SPrn)2(COD)Rh]Cl, [Mo(η-C5H4CH2CH2SPrn)2-(μ-SPrn)2Pt(PPh3)2](PF6)2, and the compound [Mo(η-C5H4(CH2)2-μ-SPh)2Cl2Rh(COD)]Cl bonds via the ring-sulphur substituents giving [Mo(η-C5H4(CH2)2-μ-SPh)2-Cl2Rh(COD)]Cl.
Bis(η-cyclopentadienyl)molybdenum Chemistry: Synthesis and Reactions of Ring-functionalised Compounds
Baretta, Andre,Chong, Kenneth S.,Cloke, F. Geoffrey N.,Feigenbaum, Alexander,Green, Malcolm L. H.
, p. 861 - 864 (2007/10/02)
Co-condensation of molybdenum atoms with spirohepta-4,6-diene gives the compound .Treatment of with iodine gives the tetraiodo-derivative (2).The tetrabromo- and tetrachloro-analogues of (2) are similarly prepared.The iodo-groups of (2) can be exchanged with the SPh radical to give which reacts with hydrogen chloride to form the compound (4).Abstraction of a halide ion from (4) gives PF6.Complex (2) reacts with dimethylamine to give 2.
