868666-27-7Relevant academic research and scientific papers
Palladium-Catalyzed Enantioselective Desymmetrizing Aza-Wacker Reaction: Development and Application to the Total Synthesis of (?)-Mesembrane and (+)-Crinane
Bao, Xu,Wang, Qian,Zhu, Jieping
, p. 1995 - 1999 (2018/01/27)
Reported is an unprecedented catalytic enantioselective desymmetrizing aza-Wacker reaction. In the presence of a catalytic amount of a newly developed Pd(CPA)2(MeCN)2 catalyst (CPA=chiral phosphoric acid), a pyrox ligand, and molecul
Regioselectivity of birch reductive alkylation of biaryls
Lebeuf, Raphael,Robert, Frederic,Landais, Yannick
, p. 4557 - 4560 (2007/10/03)
(Chemical Equation Presented) The regioselectivity of the Birch reductive alkylation of polysubstituted biaryls has been investigated. Results indicate that regioselectivity is affected by the electronic nature of substituents on both aromatic rings. The
