1476724-94-3Relevant academic research and scientific papers
Unexpected ring contraction of 1-aryl-cyclohexa-2,5-dienes under palladium catalysis
Lebeuf, Raphael,Robert, Frederic,Landais, Yannick
, p. 6 - 17 (2014/03/21)
The reaction of 1,1-disubstituted cyclohexa-2,5-dienes with aryl iodides in the presence of Pd(0) unexpectedly provided bicyclo[3.1.0] compounds in a very diastereocontrolled fashion in moderate to good yield. A tentative mechanism is proposed to rationalize this unusual reactivity of cyclohexadienes under palladium catalysis. ARKAT-USA, Inc.
