868784-34-3Relevant academic research and scientific papers
Learning about steric effects in NHC complexes from a 1D silver coordination polymer with Frechet dendrons
Ortiz, Alba M.,Gomez-Sal, Pilar,Flores, Juan C.,De Jesus, Ernesto
, p. 600 - 603 (2014)
The complex (NHC)AgBr, which bears G1 poly(benzyl ether) dendritic substituents in the NHC ligand, forms a 1D coordination polymer based on unusual zigzag -Ag-halide- chains. The asymmetric distribution of the volume buried by the NHC ligand in the Ag coordination sphere is important to explain the formation of this structure. A Vbur eccentricity parameter has been introduced and used in conjunction with the %Vbur descriptor to analyze the X-ray structures of 100 (NHC)AgX complexes.
Dendrimer N-heterocyclic carbene complexes with rhodium(I) at the core
Fujihara, Tetsuaki,Obora, Yasushi,Tokunaga, Makoto,Sato, Hiromichi,Tsuji, Yasushi
, p. 4526 - 4528 (2007/10/03)
Novel dendrimer N-heterocyclic carbene complexes with rhodium(I) located at the core were synthesized, and a positive dendrimer effect was found in the hydrosilylation of ketones catalyzed by them. The Royal Society of Chemistry 2005.
