86883-59-2Relevant articles and documents
COHALOGENATION DE CETONES α, β-ETHYLENIQUES DANS LE THF
Bertrand, M.,Dulcere, J-P,Rodriguez, J.,Zahra, J-P
, p. 1967 - 1970 (1983)
Chlorination of α, β-unsaturated ketones 2a-e at -80 degC in THF gives rise exclusively to cohalogenation products 3a-e.The reaction is regiospecific.
Cohalogenation of α,β-unsaturated ketones.
Dulcere, J. P.,Mihoubi, M. N.,Rodriguez, J.
, p. 280 - 284 (2007/10/02)
α,β-unsaturated ketones selectively react by cohalogenation reaction with halogens and solvents such as ethers or alcohols to afford corresponding α-bromo-β-alkoxyketones.Keywords: α,β-unsaturated ketones / cohalogenation