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CAS

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86885-02-1

N-{1-[3-(tert-Butyl-dimethyl-silanyloxy)-propyl]-pent-4-enyl}-S-trityl-thiohydroxylamine is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 86885-02-1 Structure

  • Basic information

    1. Product Name: N-{1-[3-(tert-Butyl-dimethyl-silanyloxy)-propyl]-pent-4-enyl}-S-trityl-thiohydroxylamine
    2. Synonyms: N-{1-[3-(tert-Butyl-dimethyl-silanyloxy)-propyl]-pent-4-enyl}-S-trityl-thiohydroxylamine
    3. CAS NO:86885-02-1
    4. Molecular Formula:
    5. Molecular Weight: 531.878
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 86885-02-1.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: N-{1-[3-(tert-Butyl-dimethyl-silanyloxy)-propyl]-pent-4-enyl}-S-trityl-thiohydroxylamine(CAS DataBase Reference)
    10. NIST Chemistry Reference: N-{1-[3-(tert-Butyl-dimethyl-silanyloxy)-propyl]-pent-4-enyl}-S-trityl-thiohydroxylamine(86885-02-1)
    11. EPA Substance Registry System: N-{1-[3-(tert-Butyl-dimethyl-silanyloxy)-propyl]-pent-4-enyl}-S-trityl-thiohydroxylamine(86885-02-1)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 86885-02-1(Hazardous Substances Data)

86885-02-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 86885-02-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,6,8,8 and 5 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 86885-02:
(7*8)+(6*6)+(5*8)+(4*8)+(3*5)+(2*0)+(1*2)=181
181 % 10 = 1
So 86885-02-1 is a valid CAS Registry Number.

86885-02-1Upstream product

86885-02-1Relevant articles and documents

Studies on the Development of the Tritylsulfenyl Group as a Nitrogen Protecting Group and Application in a Synthesis of δ-Coniceine

Branchaud, Bruce P.

, p. 3538 - 3544 (1983)

The (triphenylmethyl)sulfenyl (tritylsulfenyl, TRS) group was found to posses properties which should make it useful as a nitrogen protecting group.The almost instantaneous reaction of TrSCl (6) with amines produced the corresponding triphenylmethanesulfenamides.The TRS group was found to render the nitrogen atom nonbasic and relatively nonnucleophilic, was stable to aqueous acid, aqueous base, and various reducing agents, and was moderately stable to Moffat oxidation conditions.The TRS group could be cleaved under mild conditions, generating the amine with either CuCl2/EtOH-THF, HI/THF-H2O, or trimethylsilyl iodide (Me3SiI)/CH2Cl2.A synthesis of δ-coniceine (16) illustrates carbon-carbon bond formation with tritylsulfenimine methodology and the utility of the tritylsulfenyl group as a nitrogen protecting group.

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