868961-34-6Relevant articles and documents
Lipase active site covalent anchoring of Rh(NHC) catalysts: Towards chemoselective artificial metalloenzymes
Basauri-Molina,Riemersma,Würdemann,Kleijn,Klein Gebbink
supporting information, p. 6792 - 6795 (2015/04/22)
A Rh(NHC) phosphonate complex reacts with the lipases cutinase and Candida antarctica lipase B resulting in the first (soluble) artificial metalloenzymes formed by covalent active site-directed hybridization. When compared to unsupported complexes, these
Palladium-catalyzed arylation of aldehydes with bromo-substituted 1,3-diaryl-imidazoline carbene ligand
Yamamoto, Tetsuya,Furusawa, Takuma,Zhumagazin, Azamat,Yamakawa, Tetsu,Oe, Yohei,Ohta, Tetsuo
, p. 19 - 26 (2015/02/19)
The combination of 0 valent palladium precursor and bromo-substituted 1,3-diaryl-imidazoline carbene ligand precursor such as 1-(2-bromophenyl)-3-(2,6-diisopropylphenyl)-imidazolinium chloride 1a exhibited high catalytic activity for the 1,2-addition of arylboronic acids to aldehydes including aqueous formaldehyde.
Homodinuclear ruthenium catalysts for dimer ring-closing metathesis
Tzur, Eyal,Ben-Asuly, Amos,Diesendruck, Charles E.,Goldberg, Israel,Lemcoff, N. Gabriel
supporting information; experimental part, p. 6422 - 6425 (2009/03/11)
(Chemical Equation Presented) Two ring or not to ring: Novel diruthenium olefin metathesis catalysts show a tendency to avoid oligomerization and favor cyclic dimerization when the distances between the ruthenium centers and between the diene extremities match (see scheme).