869000-75-9Relevant academic research and scientific papers
Exploring new uses for C-H amination: Ni-catalyzed cross-coupling of cyclic sulfamates
Wehn, Paul M.,Du Bois
, p. 4685 - 4688 (2007/10/03)
(Chemical Equation Presented) Benzene-fused cyclic sulfamates are prepared from ortho-substituted phenolic starting materials through selective C-H amination or olefin aziridination. These unique heterocycles will engage in Ni-catalyzed cross-coupling reactions with aryl- and alkyl-Grignard reagents. Application of modern tools for C-N and C-C bond formation thus makes readily available functional amine derivatives and augments the possible uses for C-H amination in synthesis.
