869199-40-6Relevant academic research and scientific papers
A new protocol for the consecutive α- and β-activation of propiolates towards electrophiles, involving conjugate addition of tertiary amines and intramolecular silyl migration
Matsuya, Yuji,Hayashi, Kousuke,Nemoto, Hideo
, p. 5408 - 5418 (2007/10/03)
Herein, we present a novel approach for the consecutive α- and β-activation of conjugated alkynes and demonstrate the application of this methodology towards the C-C bond-forming reactions of propiolates. This new concept is based on the 1,4-addition of a
