86934-36-3

Upstream product

• 766-08-5 methylphenylsilane 
• 100-52-7 benzaldehyde 
• 100-51-6 benzyl alcohol 
• 3027-21-2 dimethoxy(methyl)phenylsilane 
• 149-74-6 dichloromethylphenylsilane 
• 86945-06-4 Bis-(1-methoxy-2-methyl-propenyloxy)-methyl-phenyl-silane 

Relevant academic research and scientific papers

Photoactivated silicon-oxygen and silicon-nitrogen heterodehydrocoupling with a commercially available iron compound

Silicon-oxygen and silicon-nitrogen heterodehydrocoupling catalyzed by the commercially available cyclopentadienyl dicarbonyl iron dimer [CpFe(CO)2]2 (1) under photochemical conditions is reported. Reactions between alcohols and PhSi

HYDROXIDE-CATALYZED FORMATION OF SILICON-OXYGEN BONDS BY DEHYDROGENATIVE COUPLING OF HYDROSILANES AND ALCOHOLS

The present disclosure is directed to methods for dehydrogenatively coupled hydrosilanes and alcohols, the methods comprising contacting an organic substrate having at least one organic alcohol moiety with a mixture of at least one hydrosilane and sodium and/or potassium hydroxide, the contacting resulting in the formation of a dehydrogenatively coupled silyl ether. The disclosure further described associated compositions and methods of using the formed products.

Hydridosilylamido complexes of Ta and Mo isolobal with Berry's zirconocenes: Syntheses, β-Si-H agostic interactions, catalytic hydrosilylation, and insight into mechanism

The syntheses of novel Group 5 and Group 6 hydrosilylamido complexes of the type R(ArN)M{N(tBu)SiMe2-H}X (M = Ta, R = Cp; M = Mo, R = ArN; X = Cl, H, OBn, Me) are described. The various substituents in the X position seem to play the

Sodium Hydroxide Catalyzed Dehydrocoupling of Alcohols with Hydrosilanes

An O-Si bond construction protocol employing abundantly available and inexpensive NaOH as the catalyst is described. The method enables the cross-dehydrogenative coupling of an alcohol and hydrosilane to directly generate the corresponding silyl ether under mild conditions and without the production of stoichiometric salt byproducts. The scope of both coupling partners is excellent, positioning the method for use in complex molecule and materials science applications. A novel Si-based cross-coupling reagent is also reported.

PRODUCTION METHOD FOR ALKOXYSILANES

Provided is a method for efficiently producing alkoxysilanes that are useful as various functional chemicals. In order to produce alkoxysilanes efficiently, an ethoxy- or methoxysilane and an alcohol are caused to react using, as a catalyst, for instance an inorganic solid acid having a regular-pore and/or layered structure. Zeolites, montmorillonites or the like can be used as the inorganic solid acid. When a zeolite is used as the catalyst, the silica/alumina ratio of the zeolite ranges preferably from 5 to 1000. The reaction can be promoted through irradiation of microwaves.

Alkoxysilane, [...] acids and its manufacturing method (by machine translation)

PROBLEM TO BE SOLVED: alkylalkoxysilane compounds useful as a chemical product having various functions, and [...] or obtained from the same and to provide a manufacturing method thereof. SOLUTION: the alkylalkoxysilane, or a methoxy group and an ethoxy group, an alkyl group oxystyrene, thioalkyl group, on the same silicon atom or an alkyl group halogenopyridine structure having, for example, a plurality of silane-based or methoxysalicylic naphtholsulfonic, regular porous structure having a solid acid and alcohol in the presence of catalyst inorg. by reaction can be produced. Furthermore, water and the like of [...] alkylalkoxysilane obtained by reaction, is allowed to coexist with acid or the like can be performed efficiently. Selected drawing: fig. 1 (by machine translation)

Highly efficient large bite angle diphosphine substituted molybdenum catalyst for hydrosilylation

Treatment of the complex Mo(NO)Cl3(NCMe)2 with the large bite angle diphosphine, 2,2′-bis(diphenylphosphino)diphenylether (DPEphos) afforded the dinuclear species [Mo(NO)(PaP)Cl 2]2[μCl]2 (PaP = DPEph

Cp(Pri2MeP)FeH2SiR3: Nonclassical iron silyl dihydride

Reactions of a new borohydride complex 2 with hydrosilanes afford half-sandwich dihydride silyl complexes 3a-f. According to X-ray and DFT evidence complexes 3 have unprecedented double H·...H interligand interactions. Copyright

Catalytic reduction of benzoate esters and lactones in the presence of PhMeSiH2 and a titanocene-based catalyst

PhMeSiH2 reduces ethyl benzoate in the presence of a Cp2TiMe2 (Cp = η5-cyclopentadienyl) catalyst to give PhMeSi(OEt)(OCH2Ph) (1). Small to moderate amounts of toluene are also produced, depending on the reaction conditions. Under 40 psi of H2 the same reaction gives quantitative reduction of the ester to toluene. PhCHO is reduced, under the same conditions as the ester, to a mixture of PhMeSi(OCH2Ph)2 and toluene in proportions similar to that observed with the ester. A stoichiometric reaction of PhMeSiH2, PhCOOEt, and Cp2TiMe2 resulted in the formation of known [Cp2Ti(OEt)]2 (2) in 75% isolated yield. A mechanism is proposed in which the C=O of the ester inserts into a Ti-H bond. A Ti-mediated transfer of the ethoxy group from the resulting (α-ethoxy)benzyloxytitanium intermediate to silicon produces PhMeSi(OEt)H and PhCHO. 1 is generated via hydrosilation of PhCHO by PhMeSi(OEt)H. Both β- and γ-butyrolactones react with PhMeSiH2 in the presence of a catalytic amount of Cp2TiMe2 to produce copolymers -[O-PhMeSi-O(CH2)3CHR]n- (R = H, 3; R = Me, 4) (Mw ≈ ×103; Mw/Mn ≈ 1.3). A mechanism analogous to that proposed for the ethyl benzoate reduction is proposed. A reaction of PhMeSiH2 and γ-butyrolactone with a stoichiometric amount of Cp2TiMe2 in the presence of tetrahydofuran (THF) produces Cp2Ti(μ-H)(μ-η1,η5-C 5H4)Ti(OC4H8)Cp (5) (65% isolated yield) whose structure is determined by X-ray crystallography.