86943-12-6

Basic information

• Product Name: threo-N,N-dimethyl-2-phenyl-3-methylthiopent-4-enamide
• Synonyms: threo-N,N-dimethyl-2-phenyl-3-methylthiopent-4-enamide
• CAS NO: 86943-12-6
• Molecular Weight: 295.448
• Mol File: 86943-12-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: threo-N,N-dimethyl-2-phenyl-3-methylthiopent-4-enamide(CAS DataBase Reference)
• NIST Chemistry Reference: threo-N,N-dimethyl-2-phenyl-3-methylthiopent-4-enamide(86943-12-6)
• EPA Substance Registry System: threo-N,N-dimethyl-2-phenyl-3-methylthiopent-4-enamide(86943-12-6)

Safety Data

• Hazardous Substances Data: 86943-12-6(Hazardous Substances Data)

Upstream product

• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 17709-95-4 N,N-dimethyl-2-phenylethanethioamide 
• 19627-30-6 cinnamyl tosylate 

Relevant articles and documents

Diastereoselective α Allylation of Secondary and Tertiary Thioamides via Thio-Claisen Rearrangement. A Structural Proof of Z Secondary Thioamide Dianions and Z Tertiary Thioamide Anions

Highly diastereoselective α allylation of secondary and tertiary thioamides is achieved by making use of thio-Claisen rearrangement.From the correlation between the diastereoselectivities in products and the structures of allylating agents, the Z structures of secondary thioamide dianion (ca. 100percent Z) and tertiary thioamide anion (>97percent Z) are concluded.