86951-75-9Relevant academic research and scientific papers
Keten. Part 19. Reactions of 2,4,6-Trimethylbenzonitrile N-Oxide with Ketens
Evans, Andrew R.,Taylor, Giles A.
, p. 979 - 983 (2007/10/02)
Diphenylketen, t-butylcyanoketen, and dimethylketen react with the title nitrile oxide to form 1:1 adducts shown to have the oxazolinone structures (5); keten, t-butylethoxycarbonylketen, and phenyl isocyanate fail to react.The nitrile oxide is deoxygenated by diphenylketen and dimethylketen; in the latter case a new type of deoxygenation process occurs forming the unsaturated ketone (11) and thence the isoxazoline (8).
