86953-49-3

Basic information

• Product Name: N-benzyl-4-bromo-4-pentenylamine
• Synonyms: N-benzyl-4-bromo-4-pentenylamine
• CAS NO: 86953-49-3
• Molecular Weight: 254.17
• Mol File: 86953-49-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-benzyl-4-bromo-4-pentenylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzyl-4-bromo-4-pentenylamine(86953-49-3)
• EPA Substance Registry System: N-benzyl-4-bromo-4-pentenylamine(86953-49-3)

Safety Data

• Hazardous Substances Data: 86953-49-3(Hazardous Substances Data)

Upstream product

• 86953-48-2 4-bromo-pent-4-enoic acid 
• 86953-47-1 Diethyl 2-(2-bromo-2-propenyl)malonate 
• 35804-44-5 ethyl 4-bromo-4-pentenoate 
• 86954-08-7 N-benzyl-4-bromo-4-pentenamide 

Downstream Products

• 50586-10-2 1-Benzyl-3-methylenepiperidin-2-one 
• 86953-56-2 N-Benzyl-3-methyl-5,6-dihydro-2-pyridone 
• 37672-46-1 3-methyl-1-(phenylmethyl)-2-piperidinone 

Relevant articles and documents

Palladium-Catalyzed Carbonylation. A New Synthesis of α-Methylene γ-, δ-, and ε-Lactams and -Lactones Including Bicyclic Lactams of Pyrrolizidine and Indolizidine Skeletons

The insertion of carbon monoxide into vinyl halides bearing the secondary amine or alcohol with a catalytic amount of Pd(OAc)2 and PPh3 was realized to give five-, six-, and seven-membered lactams and lactones carrying α-methylene groups in fairly good yields.Bicyclic heterocycles, pyrrolizidine and indolizidine derivatives, were also synthesized from pyrrolidine and piperidine derivatives possessing vinyl halide groups in the side chain at the 2-position of the ring by means of palladium-catalyzed carbonylation.