86954-08-7

Basic information

• Product Name: N-benzyl-4-bromo-4-pentenamide
• Synonyms: N-benzyl-4-bromo-4-pentenamide
• CAS NO: 86954-08-7
• Molecular Weight: 268.153
• Mol File: 86954-08-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-benzyl-4-bromo-4-pentenamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzyl-4-bromo-4-pentenamide(86954-08-7)
• EPA Substance Registry System: N-benzyl-4-bromo-4-pentenamide(86954-08-7)

Safety Data

• Hazardous Substances Data: 86954-08-7(Hazardous Substances Data)

Upstream product

• 100-46-9 benzylamine 
• 35804-44-5 ethyl 4-bromo-4-pentenoate 
• 86953-47-1 Diethyl 2-(2-bromo-2-propenyl)malonate 
• 86953-48-2 4-bromo-pent-4-enoic acid 

Downstream Products

• 37672-46-1 3-methyl-1-(phenylmethyl)-2-piperidinone 
• 50586-10-2 1-Benzyl-3-methylenepiperidin-2-one 
• 86953-49-3 N-benzyl-4-bromo-4-pentenylamine 

Relevant articles and documents

Palladium-Catalyzed Carbonylation. A New Synthesis of α-Methylene γ-, δ-, and ε-Lactams and -Lactones Including Bicyclic Lactams of Pyrrolizidine and Indolizidine Skeletons

The insertion of carbon monoxide into vinyl halides bearing the secondary amine or alcohol with a catalytic amount of Pd(OAc)2 and PPh3 was realized to give five-, six-, and seven-membered lactams and lactones carrying α-methylene groups in fairly good yields.Bicyclic heterocycles, pyrrolizidine and indolizidine derivatives, were also synthesized from pyrrolidine and piperidine derivatives possessing vinyl halide groups in the side chain at the 2-position of the ring by means of palladium-catalyzed carbonylation.