86953-52-8

Basic information

• Product Name: N-Benzyl-2-(2-bromo-2-propenyl)cyclohexylamine
• Synonyms: N-Benzyl-2-(2-bromo-2-propenyl)cyclohexylamine
• CAS NO: 86953-52-8
• Molecular Weight: 308.261
• Mol File: 86953-52-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-Benzyl-2-(2-bromo-2-propenyl)cyclohexylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-Benzyl-2-(2-bromo-2-propenyl)cyclohexylamine(86953-52-8)
• EPA Substance Registry System: N-Benzyl-2-(2-bromo-2-propenyl)cyclohexylamine(86953-52-8)

Safety Data

• Hazardous Substances Data: 86953-52-8(Hazardous Substances Data)

Upstream product

• 53626-84-9 2-(2-bromo-2-propen-1-yl)cyclohexanone 
• 1125-99-1 1-(1-Cyclohexen-1-yl)pyrrolidine 
• 86953-53-9 Benzyl-[2-(2-bromo-allyl)-cyclohex-(Z)-ylidene]-amine 

Downstream Products

• 86953-55-1 N-Benzyl-3-methyleneoctahydro-2-quinolone 
• 86953-58-4 N-Benzyl-3-methyl-4a,5,6,7,8,8a-hexahydro-2-quinolone 

Relevant articles and documents

Palladium-Catalyzed Carbonylation. A New Synthesis of α-Methylene γ-, δ-, and ε-Lactams and -Lactones Including Bicyclic Lactams of Pyrrolizidine and Indolizidine Skeletons

The insertion of carbon monoxide into vinyl halides bearing the secondary amine or alcohol with a catalytic amount of Pd(OAc)2 and PPh3 was realized to give five-, six-, and seven-membered lactams and lactones carrying α-methylene groups in fairly good yields.Bicyclic heterocycles, pyrrolizidine and indolizidine derivatives, were also synthesized from pyrrolidine and piperidine derivatives possessing vinyl halide groups in the side chain at the 2-position of the ring by means of palladium-catalyzed carbonylation.