86953-66-4

Upstream product

• 86954-09-8 N-benzyl-3-((tetrahydro-2H-pyran-2-yl)oxy)propane-1-amine 
• 501-53-1 benzyl chloroformate 
• 4720-29-0 3-(benzylamino)propan-1-ol 
• 100-52-7 benzaldehyde 
• 86953-65-3 N-Benzyl-N-<(benzyloxy)carbonyl>-3-<(tetrahydro-2H-pyran-2-yl)oxy>propylamine 

Downstream Products

• 86953-67-5 N-Benzyl-N<(benzyloxy)carbonyl>-3-bromopropylamine 
• 272118-24-8 3-[3-(benzyl-benzyloxycarbonyl-amino)-propoxy]-2-tert-butoxycarbonylamino-propionic acid methyl ester 
• 86953-68-6 4-Acetyl-N-benzyl-N-<(benzyloxy)carbonyl>-5-oxohexylamine 
• 1242437-76-8 N-benzyl-N-benzyloxycarbonyl-3-aminopropyl 2-azido-3,6-di-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-6-O-levulinoyl-1-thio-α-L-idopyranoside 
• 1242437-78-0 N-benzyl-N-benzyloxycarbonyl-3-aminopropyl 2-azido-3,6-di-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-6-O-levulinoyl-β-D-glucopyranoside 
• 1334709-82-8 C₆₄H₇₈N₄O₁₆Si 
• 1334709-66-8 N-(benzyl)-benzyloxycarbonyl-3-aminopropyl 6-O-acetyl-2-azido-3-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-6-O-levulinoyl-α-L-idopyranoside 
• 1334709-60-2 N-(benzyl)-benzyloxycarbonyl-3-aminopropyl 2-azido-3-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-6-O-(2,2,2-trichloroethylsulfuryl)-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-6-O-levulinoyl-β-D-glucopyranoside 

Relevant academic research and scientific papers

Terminal-Selective C(sp3)-H Arylation: NiH-Catalyzed Remote Hydroarylation of Unactivated Internal Olefins

A terminal-selective migratory hydroarylation of unactivated olefins has been developed though a NiH-catalyzed alkene isomerization-hydroarylation relay process. This sp3C-H arylation was achieved with a simple pyrox ligand under mild conditions. The practicality and synthetic flexibility of the method is highlighted by the successful regioconvergent conversion of isomeric mixtures of alkenes to value-added linear arylation products on a gram scale.

The first asymmetric total synthesis of lycoposerramine-R

The first asymmetric total synthesis of lycoposerramine-R, a Lycopodium alkaloid possessing a novel skeleton, was accomplished by a strategy featuring the stereoselective intramolecular aldol cyclization giving a cis-fused 5/6 bicyclic skeleton and a new method for the construction of the pyridone ring via the aza-Wittig reaction.

Palladium-Catalyzed Carbonylation. A New Synthesis of α-Methylene γ-, δ-, and ε-Lactams and -Lactones Including Bicyclic Lactams of Pyrrolizidine and Indolizidine Skeletons

The insertion of carbon monoxide into vinyl halides bearing the secondary amine or alcohol with a catalytic amount of Pd(OAc)2 and PPh3 was realized to give five-, six-, and seven-membered lactams and lactones carrying α-methylene groups in fairly good yields.Bicyclic heterocycles, pyrrolizidine and indolizidine derivatives, were also synthesized from pyrrolidine and piperidine derivatives possessing vinyl halide groups in the side chain at the 2-position of the ring by means of palladium-catalyzed carbonylation.