869660-22-0

Basic information

• Product Name: bis(p-aminoacetophenone oxime-5-nitrosalicylaldiminato)nickel(II)
• CAS NO: 869660-22-0
• Molecular Weight: 655.246
• Mol File: 869660-22-0.mol

Chemical Properties

• CAS DataBase Reference: bis(p-aminoacetophenone oxime-5-nitrosalicylaldiminato)nickel(II)(CAS DataBase Reference)
• NIST Chemistry Reference: bis(p-aminoacetophenone oxime-5-nitrosalicylaldiminato)nickel(II)(869660-22-0)
• EPA Substance Registry System: bis(p-aminoacetophenone oxime-5-nitrosalicylaldiminato)nickel(II)(869660-22-0)

Safety Data

• Hazardous Substances Data: 869660-22-0(Hazardous Substances Data)

Upstream product

• 869660-20-8 5-nitrosalicylidene-p-aminoacetophenone oxime 
• 6018-89-9 nickel(II) acetate tetrahydrate 

Relevant articles and documents

Studies on mononuclear chelates derived from substituted sdchiff bases ligands (Part 3). Synthesis and characterization of a new 5-nitrosalicylidene-p- aminoacetophenoneoxime and its complexes with Co(II), Ni(II), Cu(II), and Zn(II)

A new ligand, 5-nitrosalicylidene-p-aminoacetophenoneoxime (HL), was synthesized from p-aminoacetophenoneoxime and 5-nitrosalicylaldehyde under reflux in absolute EtOH at 60°C for 3 h. Mononuclear complexes with a metal : ligand ratio of 1 : 2 were prepared with CoII, Ni II,CuII, and ZnII salts. Their structures were determined on the basis of elemental analyses, IR, 1H and 13C NMR, electronic spectra, magnetic susceptibility measurements, molar conductivity, and thermogravimetric analyses. According to the results, two ligands were suggested to be coordinated to each metal atom by phenolic oxygen and imino nitrogen to form high-spin tetrahedral complexes with cobalt(II), nickel(II), and copper(II) while forming a diamagnetic complex with zinc(II).