869728-94-9

Basic information

• Product Name: 4-hydroxy-3-methoxycinnamyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside
• Synonyms: 4-hydroxy-3-methoxycinnamyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside
• CAS NO: 869728-94-9
• Molecular Weight: 510.495
• Mol File: 869728-94-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-hydroxy-3-methoxycinnamyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 4-hydroxy-3-methoxycinnamyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside(869728-94-9)
• EPA Substance Registry System: 4-hydroxy-3-methoxycinnamyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside(869728-94-9)

Safety Data

• Hazardous Substances Data: 869728-94-9(Hazardous Substances Data)

Upstream product

• 50-99-7 D-glucose 
• 7368-78-7 4-bromoguaiacol 
• 2595-07-5 allyl β-D-glucopyranoside 
• 864757-97-1 2-(4-bromo-2-methoxyphenoxy)tetrahydropyran 
• 10343-15-4 Acetic acid (2R,3R,4S,5R,6R)-3,5-diacetoxy-2-acetoxymethyl-6-allyloxy-tetrahydro-pyran-4-yl ester 
• 182344-21-4 (4-hydroxy-3-methoxyphenyl)boronic acid 

Downstream Products

• 113349-27-2 3-(4-hydroxy-3-methoxy)-phenyl-2E-propenyl-1β-D-glucopyranoside 

Relevant articles and documents

Simple preparation of phenylpropenoid β-D-glucopyranoside congeners by Mizoroki-Heck type reaction using organoboron reagents

Palladium(II)-catalyzed carbon-carbon bond formation between allyl 2,3,4,6-tetra-O-acetyl-β-d-glucopyranoside (3) and arylboronic acid congeners gave the corresponding cinnamyl 2,3,4,6-tetra-O-acetyl- β-d-glucopyranosides (4a-m) in good yield. Among them, coupling products 4a-m were converted to not only the naturally occurring phenylpropenoid β-d-glucopyranoside analogues (1a-e) but also the unnaturally ones (1f-m).