869808-67-3Relevant academic research and scientific papers
Sterically directed iridium-catalyzed hydrosilylation of alkenes in the presence of alkynes
Muchnij, Jill A.,Kwaramba, Farai B.,Rahaim, Ronald J.
supporting information, p. 1330 - 1333 (2014/04/03)
A selective iridium catalyzed hydrosilylation of alkenes in the presence of more reactive alkynes is described. By utilizing [IrCl(COD)]2 in the presence of excess COD, hydrosilylation of alkenes and alkynes with ethynylsilanes is achieved with
1,1- and 1,2-allylboration of alkyn-1-ylsilanes bearing Si-H functions. Electron-deficient Si-H-B bridges, and intramolecular hydrosilylation
Wrackmeyer, Bernd,Tok, Oleg L.
, p. 243 - 251 (2007/10/03)
The reactions of n-hexyn-1-ylsilanes or arylethyn-1-ylsilanes, bearing methyl groups and one (2), two (3) or three hydride functions (4) at the silicon atom, with triallylborane 1 lead primarily to products of 1,1- or 1,2-allylboration. In the alkenes (5,
