86984-22-7Relevant academic research and scientific papers
Studies on Pyrimidine Derivatives. XXXIII. Synthesis of Alkyl Pyrimidinyl Ketones by Means of Nitrosation of Alkylpyrimidines
Sakamoto, Takao,Sakasai, Takeji,Yoshizawa, Hiroshi,Tanji, Ken-Ichi,Nishimura, Sumiko,Yamanaka, Hiroshi
, p. 4554 - 4560 (2007/10/02)
The reaction of 4-alkylpyrimidines with propyl nitrite under acidic conditions followed by deoximation of the resulting ketoximes gave alkyl pyrimidinyl ketones in satisfactory yields.As compared with the direct oxidation of the alkylpyrimidines with sele
Nickel-catalyzed Addition or Coupling Reactions of Grignard Reagents with Halopyrimidines
Elmoghayar, Mohamed R. H.,Groth, Per,Undheim, Kjell
, p. 109 - 114 (2007/10/02)
Phenylmagnesium bromide with NiCl2(dppp) catalysis adds selectively to the unsubstituted position in 2,4-dichlro-5-chloro(fluoro)pyrimidine.X-Ray structure analysis of the hydrolyzed adduct shows an infinite chain by N1 - N3' hydrogen bonding.The hydrolyz
