87007-17-8Relevant academic research and scientific papers
Selective synthesis of phosphate monoesters by dehydrative condensation of phosphoric acid and alcohols promoted by nucleophilic bases
Sakakura, Akira,Katsukawa, Mikimoto,Ishihara, Kazuaki
, p. 1999 - 2002 (2005)
(Chemical Equation Presented) Phosphate monoesters are synthesized from a mixture of phosphoric acid (1 or 2 equiv) and alcohols (1 equiv) in the presence of tributylamine. The reaction is promoted by nucleophilic bases such as N-alkylimidazole and 4-(N,N-dialkylamino)pyridine. 2′,3′-I- Isopropylidene ribonucleosides are selectively converted to their 5′-monophosphates without the protection of amino groups in nucleobases.
A new method for transforming primary amines into phosphoric acid monoesters
Luo,Ganem
, p. 3145 - 3146 (2007/10/02)
Nitrosation of dibenzylphosphoramidates enables the synthesis of phosphoric acid monoesters from primary n-alkylamines in good yield.
