870091-88-6

Basic information

• Product Name: [(R)-2-(benzyloxy)-3,3-dimethylpent-4-ynyloxy]-tert-butyldimethylsilane
• Synonyms: [(R)-2-(benzyloxy)-3,3-dimethylpent-4-ynyloxy]-tert-butyldimethylsilane
• CAS NO: 870091-88-6
• Molecular Weight: 332.558
• Mol File: 870091-88-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(R)-2-(benzyloxy)-3,3-dimethylpent-4-ynyloxy]-tert-butyldimethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: [(R)-2-(benzyloxy)-3,3-dimethylpent-4-ynyloxy]-tert-butyldimethylsilane(870091-88-6)
• EPA Substance Registry System: [(R)-2-(benzyloxy)-3,3-dimethylpent-4-ynyloxy]-tert-butyldimethylsilane(870091-88-6)

Safety Data

• Hazardous Substances Data: 870091-88-6(Hazardous Substances Data)

Upstream product

• 19757-86-9 methyl 2,2-dimethyl-3-pentenoate 
• 870091-85-3 (R)-4-(benzyloxy)-3,3-dimethyl-4,5-dihydro-3H-furan-2-one 
• 870091-86-4 (R)-4-(benzyloxy)-3,3-dimethyltetrahydrofuran-2-ol 
• 72902-81-9 (R)-4-hydroxy-3,3-dimethyl-4,5-dihydro-3H-furan-2-one 

Downstream Products

• 870091-91-1 (3S,4R,9R)-1,9-bis(benzyloxy)-3,10-bis(tert-butylsilyloxy)-4,8,8-trimethyldec-6-yn-5-one 
• 870091-92-2 (3R,5S,7S,8R)-3-(benzyloxy)-7-[2-(benzyloxy)ethyl]-4,4,8-trimethyl-1,6-dioxaspiro[4.5]decan-9-one 

Relevant articles and documents

The reaction mechanism of spirocylization and stereoselectivity studies for the calyculin C16-C25 fragment

The mechanism of the double intramolecular hetero-Michael addition, a key reaction in the planned synthesis of the natural product calyculin C, has been studied by NMR. The cyclization follows Baldwin's rules and proceeds first through a six-membered ring