87015-49-4Relevant articles and documents
Conjugate addition nitro-Mannich reaction of carbon and heteroatom nucleophiles to nitroalkenes
Anderson, James C.,Kalogirou, Andreas S.,Tizzard, Graham J.
, p. 9337 - 9351 (2015/03/05)
The conjugate addition nitro-Mannich reactions of ethyl-β-nitroacrylate (1) and β-nitrostyrene (2) with electron rich aromatic nucleophiles, stabilized carbanions, alcohols, amines, thiols, and diphenyl phosphine oxide were investigated. The one pot conju
KINETIC STUDIES ON REACTION OF SULFINIC ACIDS WITH CONJUGATED ALKENES: I. KINETICS OF THE ADDITION OF ARENESULFINIC ACIDS TO β-NITROSTYRENE
Aleksiev, D. I.,Ivanova, S.,Tashkova, Kr.
, p. 73 - 76 (2007/10/02)
Addition of unsubstituted and substituted benzenesulfinic acids to β-nitrostyrene has been studied kinetically by means of ultraviolet spectrophotometry.The reaction follows the second-order kinetics: ν=k. .The dependence of rate constants on the temperature and influence of p-substituents on the kinetic parameters have been investigated.The activating energy and the enthalpy of activation are calculated in the temperature range 288-308 K. Key words: Sulfinic acids; β-nitrostyrene; reaction order; rate constants; activating energy; enthalpy of activation.