87018-30-2Relevant articles and documents
Selective bromochlorination of a homoallylic alcohol for the total synthesis of (-)-Anverene
Seidl, Frederick J.,Burns, Noah Z.
, p. 1361 - 1365 (2016)
The scope of a recently reported method for the catalytic enantioselective bromochlorination of allylic alcohols is expanded to include a specific homoallylic alcohol. Critical factors for optimization of this reaction are highlighted. The utility of the
Bromination of alkenols with the H2O2 - LiBr - CeIII and H2O2 - LiBr - CeIV systems
Nikishin,Sokova,Kapustina
, p. 459 - 463 (2013/07/05)
Reactions of alkenols with H2O2 - LiBr - Ce(NO 3)3·6H2O or H2O2 - LiBr - Ce(NH4)2(NO3)6 system led to bromination of the double bond to yield vicinal dibromoalkanols. The reaction proceeded highly selectively, no oxidation of the hydroxyl group virtually occurred.