870197-45-8

Basic information

• Product Name: [2-(4-benzyl-2-oxazoline-2-yl)ferrocenyl]diphenylphosphine
• CAS NO: 870197-45-8
• Molecular Weight: 529.401
• Mol File: 870197-45-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [2-(4-benzyl-2-oxazoline-2-yl)ferrocenyl]diphenylphosphine(CAS DataBase Reference)
• NIST Chemistry Reference: [2-(4-benzyl-2-oxazoline-2-yl)ferrocenyl]diphenylphosphine(870197-45-8)
• EPA Substance Registry System: [2-(4-benzyl-2-oxazoline-2-yl)ferrocenyl]diphenylphosphine(870197-45-8)

Safety Data

• Hazardous Substances Data: 870197-45-8(Hazardous Substances Data)

Upstream product

• 297163-59-8 (R)-3,5-dihydrodinaphtho[2,1-c:1',2'-e]selenepin 4-oxide 
• 870197-45-8 rac-[2-(4-benzyl-2-oxazoline-2-yl)ferrocenyl]diphenylphosphine 

Downstream Products

• 541540-58-3 [2-(4-benzyl-2-oxazoline-2-yl)ferrocenyl]diphenylphosphine 

Relevant articles and documents

Kinetic resolution of racemic ferrocenylphosphine compounds by enantioselective oxidation using cyclic selenoxides having a chiral ligand

Cyclic selenoxides having an optically active binaphthyl skeleton work as the reagents for enantioselective oxidation of phosphines to the corresponding phosphine oxides. Treatment of a racemic 2-oxazolin-2-ylferrocenylphosphine with one of the selenoxides in carbon tetrachloride in the presence of phenol affords the corresponding phosphine oxide together with the unreacted starting phosphine, both with moderate enantioselectivities (the phosphine oxide, up to 13% ee; the phosphine, up to 29% ee).